Functionalization of Hexa-peri-hexabenzocoronenes: Investigation of the Substituent Effects on a Superbenzene

We have demonstrated that the iridium‐catalyzed direct borylation of hexa‐peri‐hexabenzocoronene (HBC) enables regioselective introduction of boryl groups to the para‐, ortho‐, and meta‐substituted HBCs in high yields. The boryl groups have been transformed into various functionalities such as hydro...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2013-01, Vol.8 (1), p.178-190
Hauptverfasser:	Yamaguchi, Ryuichi, Ito, Satoru, Lee, Byung Sun, Hiroto, Satoru, Kim, Dongho, Shinokubo, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	aromatic substitution Chemistry density functional calculations hexa-peri-hexabenzocoronene substituent effects two-photon absorption
Online-Zugang:	Volltext
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