Stepwise Degradation of Trifluoromethyl Platinum(II) Compounds

The action of moisture on the homoleptic organoplatinum(II) compound [NBu4]2[Pt(CF3)4] (1) gives rise to the carbonyl derivative [NBu4][Pt(CF3)3(CO)] (2), which is itself moisture stable. However, treatment of compound 2 with HCl(aq) results in the formation of [NBu4][cis‐Pt(CF3)2Cl(CO)] (3), which...

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Veröffentlicht in:	Chemistry : a European journal 2013-01, Vol.19 (1), p.324-337
Hauptverfasser:	Martínez-Salvador, Sonia, Forniés, Juan, Martín, Antonio, Menjón, Babil, Usón, Isabel
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations, Divalent - chemistry Chlorofluorocarbons, Methane - chemistry Coordination Complexes - chemistry Crystallography, X-Ray CF activation CN coupling fluorinated compounds Ligands Models, Molecular Organoplatinum Compounds - chemistry platinum Platinum - chemistry Stereoisomerism transition metals
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