Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA

► Wetlands in the Goose Lake oil field have been contaminated by produced water. ► Salinity during the course of evapotranspiration increases during summer months. ► Strontium isotopes are not effected by evaporation and are sensitive indicators of produced water contamination. Groundwater, surface...

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Veröffentlicht in:Applied geochemistry 2012-12, Vol.27 (12), p.2403-2408
Hauptverfasser: Peterman, Zell E., Thamke, Joanna, Futa, Kiyoto, Preston, Todd
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container_title Applied geochemistry
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creator Peterman, Zell E.
Thamke, Joanna
Futa, Kiyoto
Preston, Todd
description ► Wetlands in the Goose Lake oil field have been contaminated by produced water. ► Salinity during the course of evapotranspiration increases during summer months. ► Strontium isotopes are not effected by evaporation and are sensitive indicators of produced water contamination. Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl−-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of 87Sr/86Sr in detecting small amounts of brine. Differences in Sr concentrations and 87Sr/86Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9mg/L, and corresponding 87Sr/86Sr values range from 0.71097 to 0.70828. The local brine has 168mg/L Sr and a 87Sr/86Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.
doi_str_mv 10.1016/j.apgeochem.2012.08.004
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subjects data collection
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
Exact sciences and technology
Geochemistry
geophysics
groundwater
isotopes
mixing
oil fields
petroleum
Pollution, environment geology
soil
solutes
strontium
surface water
title Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana, USA
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