Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission
Stepwise locking of phenyl rings of tetraphenylethene increases the emission efficiency of luminogen solutions gradually, thus verifying the restriction of intramolecular rotation (RIR) mechanism of the aggregation induced emission phenomenon. The emission of the luminogen with one "O" bri...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (86), p.10675-10677 |
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container_issue | 86 |
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container_title | Chemical communications (Cambridge, England) |
container_volume | 48 |
creator | Shi, Junqing Chang, Ning Li, Cuihong Mei, Ju Deng, Chunmei Luo, Xiaoliang Liu, Zhengping Bo, Zhishan Dong, Yong Qiang Tang, Ben Zhong |
description | Stepwise locking of phenyl rings of tetraphenylethene increases the emission efficiency of luminogen solutions gradually, thus verifying the restriction of intramolecular rotation (RIR) mechanism of the aggregation induced emission phenomenon. The emission of the luminogen with one "O" bridge could be tuned reversibly in solid state through repeated heating and grinding. |
doi_str_mv | 10.1039/c2cc35641d |
format | Article |
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The emission of the luminogen with one "O" bridge could be tuned reversibly in solid state through repeated heating and grinding.</description><subject>Agglomeration</subject><subject>Benzene Derivatives - chemistry</subject><subject>Constrictions</subject><subject>Crystallization</subject><subject>Emission</subject><subject>Ethylenes - chemistry</subject><subject>Heating</subject><subject>Locking</subject><subject>Phenyls</subject><subject>Solid state</subject><subject>Spectrometry, Fluorescence</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtLAzEUhYMoVqsbf4BkKcJoHpPMxJ0UX1Bwo-BuSJObdrSTqckM0n9vxra6NJube-53DwkHoTNKrijh6towY7iQObV76IhymWciL9_2h7tQWcFzMULHMb6TdKgoD9GIcUIpEeIIfU1b81H7Oe4WgFcL8OslDqmPuHW4gy7ojQhp7gHHDlZ4tv6pN7j3FkLstLc7hwbMQvs6NsO6ns8DzHVXtz6rve0NWAxNHWMSTtCB08sIp9s6Rq_3dy-Tx2z6_PA0uZ1mJmesy6wtraKKAZFgJHOqVE5IM5NSiplSzuk0obRI3zKKu4K7kouS5ERLq0sOfIwuNr6r0H72ELsqPcDAcqk9tH2sKJOyEErJ4n-UlCwnBWcDerlBTWhjDOCqVagbHdYJqoZMqr9MEny-9e1nDdhfdBcC_waVy4ju</recordid><startdate>20120101</startdate><enddate>20120101</enddate><creator>Shi, Junqing</creator><creator>Chang, Ning</creator><creator>Li, Cuihong</creator><creator>Mei, Ju</creator><creator>Deng, Chunmei</creator><creator>Luo, Xiaoliang</creator><creator>Liu, Zhengping</creator><creator>Bo, Zhishan</creator><creator>Dong, Yong Qiang</creator><creator>Tang, Ben Zhong</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20120101</creationdate><title>Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission</title><author>Shi, Junqing ; Chang, Ning ; Li, Cuihong ; Mei, Ju ; Deng, Chunmei ; Luo, Xiaoliang ; Liu, Zhengping ; Bo, Zhishan ; Dong, Yong Qiang ; Tang, Ben Zhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-dd8d9192e06ec62f989f56cb6665b99ffae06117158c93f73f8358040a6da83e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Agglomeration</topic><topic>Benzene Derivatives - chemistry</topic><topic>Constrictions</topic><topic>Crystallization</topic><topic>Emission</topic><topic>Ethylenes - chemistry</topic><topic>Heating</topic><topic>Locking</topic><topic>Phenyls</topic><topic>Solid state</topic><topic>Spectrometry, Fluorescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shi, Junqing</creatorcontrib><creatorcontrib>Chang, Ning</creatorcontrib><creatorcontrib>Li, Cuihong</creatorcontrib><creatorcontrib>Mei, Ju</creatorcontrib><creatorcontrib>Deng, Chunmei</creatorcontrib><creatorcontrib>Luo, Xiaoliang</creatorcontrib><creatorcontrib>Liu, Zhengping</creatorcontrib><creatorcontrib>Bo, Zhishan</creatorcontrib><creatorcontrib>Dong, Yong Qiang</creatorcontrib><creatorcontrib>Tang, Ben Zhong</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shi, Junqing</au><au>Chang, Ning</au><au>Li, Cuihong</au><au>Mei, Ju</au><au>Deng, Chunmei</au><au>Luo, Xiaoliang</au><au>Liu, Zhengping</au><au>Bo, Zhishan</au><au>Dong, Yong Qiang</au><au>Tang, Ben Zhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2012-01-01</date><risdate>2012</risdate><volume>48</volume><issue>86</issue><spage>10675</spage><epage>10677</epage><pages>10675-10677</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Stepwise locking of phenyl rings of tetraphenylethene increases the emission efficiency of luminogen solutions gradually, thus verifying the restriction of intramolecular rotation (RIR) mechanism of the aggregation induced emission phenomenon. 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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Agglomeration Benzene Derivatives - chemistry Constrictions Crystallization Emission Ethylenes - chemistry Heating Locking Phenyls Solid state Spectrometry, Fluorescence |
title | Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission |
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