Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission

Stepwise locking of phenyl rings of tetraphenylethene increases the emission efficiency of luminogen solutions gradually, thus verifying the restriction of intramolecular rotation (RIR) mechanism of the aggregation induced emission phenomenon. The emission of the luminogen with one "O" bri...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (86), p.10675-10677
Hauptverfasser: Shi, Junqing, Chang, Ning, Li, Cuihong, Mei, Ju, Deng, Chunmei, Luo, Xiaoliang, Liu, Zhengping, Bo, Zhishan, Dong, Yong Qiang, Tang, Ben Zhong
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container_end_page 10677
container_issue 86
container_start_page 10675
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Shi, Junqing
Chang, Ning
Li, Cuihong
Mei, Ju
Deng, Chunmei
Luo, Xiaoliang
Liu, Zhengping
Bo, Zhishan
Dong, Yong Qiang
Tang, Ben Zhong
description Stepwise locking of phenyl rings of tetraphenylethene increases the emission efficiency of luminogen solutions gradually, thus verifying the restriction of intramolecular rotation (RIR) mechanism of the aggregation induced emission phenomenon. The emission of the luminogen with one "O" bridge could be tuned reversibly in solid state through repeated heating and grinding.
doi_str_mv 10.1039/c2cc35641d
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source MEDLINE; Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Agglomeration
Benzene Derivatives - chemistry
Constrictions
Crystallization
Emission
Ethylenes - chemistry
Heating
Locking
Phenyls
Solid state
Spectrometry, Fluorescence
title Locking the phenyl rings of tetraphenylethene step by step: understanding the mechanism of aggregation-induced emission
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