Photoluminescence characterization and energy transfer of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors

A series of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors were synthesized by solid-state reaction method. The crystal structure, photolu- minescence emission and excitation spectra and decay times of the phosphors were carefully investigated. The results revealed that an effi- cient energy transfer occurred...

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Veröffentlicht in:Journal of rare earths 2012-08, Vol.30 (8), p.739-743
1. Verfasser: 豆喜华 赵韦人 宋恩海 邓玲玲 方夏冰 闵华初
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description A series of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors were synthesized by solid-state reaction method. The crystal structure, photolu- minescence emission and excitation spectra and decay times of the phosphors were carefully investigated. The results revealed that an effi- cient energy transfer occurred from Ce3+ to Zb3+ ions in NaBaPO4 host by means of dipole-dipole interactions and the critical distance of the energy transfer was about 0.638 nm. Moreover, the phosphor emitted strong green emission under UV excitation, indicating that the phos- phors are potentially useful as a highly efficient, green-emitting phosphor.
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source Elsevier ScienceDirect Journals; Alma/SFX Local Collection
subjects Crystal structure
Decay
Emission
Energy transfer
Excitation spectra
luminescence
optical materials
Phosphors
Photoluminescence
Rare earth metals
rare earths
偶极相互作用
光致发光特性
发射光谱
固相反应法
晶体结构
能量转移效率
荧光激发
荧光粉
title Photoluminescence characterization and energy transfer of NaBa1-x-yPO4:xCe3+, yTb3+ phosphors
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