Precision synthesis of (1>6)- alpha -D-glucopyranan by cationic ring-opening polymerization of 1,6-anhydro-2,3,4-tri-O-allyl-B-D-glucopyranose

The ring-opening polymerization of 1,6-anhydro-2,3,4-tri-O-allyl- beta -D-glucopyranose (2) has been carried out using various cationic initiators. For the condition of [2]/[BF3.OEt2] = 20 at -15C for 90 h, the polymer yield, Mw and Mw/Mn of the polymer obtained were 79%, 215,600 and 3.45, respectiv...

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Veröffentlicht in:	Macromolecular symposia. 2002-05, Vol.181 (1), p.101-106
Hauptverfasser:	Kakuchi, Toyoji, Kusuno, Atsushi, Mori, Manami, Satoh, Toshifumi, Miura, Masakatsu, Sharfuddin, Mohd, Kaga, Harumi
Format:	Artikel
Sprache:	eng
Schlagworte:	Bulk polymerization Cationic Conversion Initiators Manganese Polymerization Solution polymerization Synthesis
Online-Zugang:	Volltext
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