Batch and Semicontinuous Styrene-Butadiene Emulsion Copolymerization Reactions
In this work an experimental and simulation study of batch and semicontinuous styrene/butadiene emulsion copolymerization process was developed. The mathematical model combines the classical emulsion copolymerization equations, with mass balances, partitioning of components among all liquid phases,...
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| Veröffentlicht in: | Macromolecular symposia. 2006-11, Vol.243 (1), p.114-122 |
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| container_title | Macromolecular symposia. |
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| creator | Filho, Aluisio Pinelli Araujo, Odair Giudici, Reinaldo Sayer, Claudia |
| description | In this work an experimental and simulation study of batch and semicontinuous styrene/butadiene emulsion copolymerization process was developed. The mathematical model combines the classical emulsion copolymerization equations, with mass balances, partitioning of components among all liquid phases, micellar and homogenous nucleation mechanisms and mass transfer equations between liquid and gaseous phases. Simulation results show good agreement with experimental measurements of conversion, average particle diameter and pressure. |
| doi_str_mv | 10.1002/masy.200651112 |
| format | Article |
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Simulation results show good agreement with experimental measurements of conversion, average particle diameter and pressure.</description><subject>Computer simulation</subject><subject>Copolymerization</subject><subject>emulsion polymerization</subject><subject>Emulsions</subject><subject>gas-liquid mass transfer</subject><subject>Liquids</subject><subject>Mathematical analysis</subject><subject>Mathematical models</subject><subject>modeling</subject><subject>Nucleation</subject><subject>Phases</subject><subject>semicontinuous</subject><subject>styrene/butadiene</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkM1Lw0AUxIMoWKtXzzl6Sd19m2ySY1trFWqFRil6WV53N7iaj5pN0PjXmxARb57e8JjfMIzjnFMyoYTAZY62nQAhPKCUwoEzogFQj8WEHHaaAHiUcXLsnFj7SgiJ45COnPUMa_niYqHcROdGlkVtiqZsrJvUbaUL7c2aGpXplLvIm8yasnDn5b7M2lxX5gvr_rHRKHthT52jFDOrz37u2Hm8XjzMb7zV_fJ2Pl15sqsAHmORHwQgMY1SJUHFsY8hD5BSrlBxwn2FEAUSfJCaAgVUTO4iyfROpRpTNnYuhtx9Vb432tYiN1bqLMNCd-UFBc5DHyIWdNbJYJVVaW2lU7GvTI5VKygR_XCiH078DtcB8QB8mEy3_7jF3TR5-st6A2tsrT9_WazeBA9ZGIjteimuwjVsnkkituwbhLmDLw</recordid><startdate>200611</startdate><enddate>200611</enddate><creator>Filho, Aluisio Pinelli</creator><creator>Araujo, Odair</creator><creator>Giudici, Reinaldo</creator><creator>Sayer, Claudia</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200611</creationdate><title>Batch and Semicontinuous Styrene-Butadiene Emulsion Copolymerization Reactions</title><author>Filho, Aluisio Pinelli ; Araujo, Odair ; Giudici, Reinaldo ; Sayer, Claudia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3602-3384552caf8fdc2d994a765a116dad6064da285c242ce1212ad3cb8c3ebdfeaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Computer simulation</topic><topic>Copolymerization</topic><topic>emulsion polymerization</topic><topic>Emulsions</topic><topic>gas-liquid mass transfer</topic><topic>Liquids</topic><topic>Mathematical analysis</topic><topic>Mathematical models</topic><topic>modeling</topic><topic>Nucleation</topic><topic>Phases</topic><topic>semicontinuous</topic><topic>styrene/butadiene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Filho, Aluisio Pinelli</creatorcontrib><creatorcontrib>Araujo, Odair</creatorcontrib><creatorcontrib>Giudici, Reinaldo</creatorcontrib><creatorcontrib>Sayer, Claudia</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Filho, Aluisio Pinelli</au><au>Araujo, Odair</au><au>Giudici, Reinaldo</au><au>Sayer, Claudia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Batch and Semicontinuous Styrene-Butadiene Emulsion Copolymerization Reactions</atitle><jtitle>Macromolecular symposia.</jtitle><addtitle>Macromol. 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| language | eng |
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| subjects | Computer simulation Copolymerization emulsion polymerization Emulsions gas-liquid mass transfer Liquids Mathematical analysis Mathematical models modeling Nucleation Phases semicontinuous styrene/butadiene |
| title | Batch and Semicontinuous Styrene-Butadiene Emulsion Copolymerization Reactions |
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