Living Olefin Polymerisation and Block Copolymer Synthesis in the Presence of a Single-site Catalyst Containing a Phenoxyimine Ligand

A new phenoxyimine catalyst (Bis‐(N‐(3′,5′‐diiodo‐salicylidene)‐2,6‐difluoroaniline)‐titanium(IV)‐dichloride) has been synthesised and characterised. After activation with MAO, it was used as highly active catalyst in living olefin polymerisation of ethylene and propylene. Ultra‐high molecular weigh...

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