Fluorenyl based syndiotactic specific metallocene catalysts structural features, origin of syndiospecificity

The stereochemistry of propylene insertion/propagation reactions with a variety of Cs symmetric fluorenyl‐ containing single site catalysts is discussed. Our recent results indicate that independent of the chemical composition of the ancillary ligand fragments, or nature of the transition metal, act...

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Veröffentlicht in:	Macromolecular symposia. 2004-06, Vol.213 (1), p.157-172
Hauptverfasser:	Razavi, Abbas, Bellia, Vincenzo, De Brauwer, Yves, Hortmann, Kai, Peters, Liliane, Sirole, Sabine, Van Belle, Stephan, Thewalt, Ulf
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Insertion Ligands mechanism metallocene Metallocenes polypropylene Symmetry syndiospecificity Syndiotacticity Transition metals
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