Metal-containing conjugated oligo- and polythiophenes

Conjugated polymers containing metal groups are an important class of new materials that may find application as sensors, non‐linear optical materials and in molecular electronics. Polythiophenes are an extensively studied class of conjugated polymers, that can be easily modified synthetically, and...

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Veröffentlicht in:Macromolecular symposia. 2004-03, Vol.209 (1), p.133-140
Hauptverfasser: Moorlag, Carolyn, Clot, Olivier, Zhu, Yongbao, Wolf, Michael O.
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container_title Macromolecular symposia.
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creator Moorlag, Carolyn
Clot, Olivier
Zhu, Yongbao
Wolf, Michael O.
description Conjugated polymers containing metal groups are an important class of new materials that may find application as sensors, non‐linear optical materials and in molecular electronics. Polythiophenes are an extensively studied class of conjugated polymers, that can be easily modified synthetically, and may be prepared using a variety of methods. Metal groups pendant to polythiophene backbones modulate the electronic, optical and redox properties of the conjugated backbone and can introduce novel structural motifs to these materials. Functionalization of oligo‐ and polythiophenes by Fe, Pd and Ru containing groups is discussed, along with the properties of some of these materials.
doi_str_mv 10.1002/masy.200450509
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source Wiley Online Library Journals Frontfile Complete
subjects Backbone
conductivity
conjugated polymers
Electronics
electropolymerization
Iron
metal-containing polymers
Molecular electronics
Nonlinearity
Optical properties
Palladium
Polymers
redox properties
title Metal-containing conjugated oligo- and polythiophenes
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