Metal-containing conjugated oligo- and polythiophenes
Conjugated polymers containing metal groups are an important class of new materials that may find application as sensors, non‐linear optical materials and in molecular electronics. Polythiophenes are an extensively studied class of conjugated polymers, that can be easily modified synthetically, and...
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Veröffentlicht in: | Macromolecular symposia. 2004-03, Vol.209 (1), p.133-140 |
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creator | Moorlag, Carolyn Clot, Olivier Zhu, Yongbao Wolf, Michael O. |
description | Conjugated polymers containing metal groups are an important class of new materials that may find application as sensors, non‐linear optical materials and in molecular electronics. Polythiophenes are an extensively studied class of conjugated polymers, that can be easily modified synthetically, and may be prepared using a variety of methods. Metal groups pendant to polythiophene backbones modulate the electronic, optical and redox properties of the conjugated backbone and can introduce novel structural motifs to these materials. Functionalization of oligo‐ and polythiophenes by Fe, Pd and Ru containing groups is discussed, along with the properties of some of these materials. |
doi_str_mv | 10.1002/masy.200450509 |
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Polythiophenes are an extensively studied class of conjugated polymers, that can be easily modified synthetically, and may be prepared using a variety of methods. Metal groups pendant to polythiophene backbones modulate the electronic, optical and redox properties of the conjugated backbone and can introduce novel structural motifs to these materials. 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Functionalization of oligo‐ and polythiophenes by Fe, Pd and Ru containing groups is discussed, along with the properties of some of these materials.</description><subject>Backbone</subject><subject>conductivity</subject><subject>conjugated polymers</subject><subject>Electronics</subject><subject>electropolymerization</subject><subject>Iron</subject><subject>metal-containing polymers</subject><subject>Molecular electronics</subject><subject>Nonlinearity</subject><subject>Optical properties</subject><subject>Palladium</subject><subject>Polymers</subject><subject>redox properties</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkMFPwjAUhxujiYhePe_opfi6rlt7JChgAngQI56aruugOFZcR3T_vSMzxJun90ve9728_BC6JTAgAOH9TvlmEAJEDBiIM9QjLCSYCoDzNkMYYkJjuERX3m8BQIiE9BCbm1oVWLuyVra05Tpo4_awVrXJAlfYtcOBKrNg74qm3li335jS-Gt0kavCm5vf2Uev48flaIpnz5On0XCGNRVc4CzlKWMR55TmVBvFiVBRGAMQynWUEtZ-QTUIorMsVu2apcToNBKEMs7zmPbRXXd3X7nPg_G13FmvTVGo0riDlySM4yQCSnmLDjpUV877yuRyX9mdqhpJQB77kcd-5KmfVhCd8GUL0_xDy_nw5f2vizvX-tp8n1xVfcg4oQmTb4uJnI4nq6VYLeQD_QEzkng-</recordid><startdate>200403</startdate><enddate>200403</enddate><creator>Moorlag, Carolyn</creator><creator>Clot, Olivier</creator><creator>Zhu, Yongbao</creator><creator>Wolf, Michael O.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200403</creationdate><title>Metal-containing conjugated oligo- and polythiophenes</title><author>Moorlag, Carolyn ; Clot, Olivier ; Zhu, Yongbao ; Wolf, Michael O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3989-db8b5548833f3cea819a42600138c4b150093c091cdd6aa815b1ecb4913588f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Backbone</topic><topic>conductivity</topic><topic>conjugated polymers</topic><topic>Electronics</topic><topic>electropolymerization</topic><topic>Iron</topic><topic>metal-containing polymers</topic><topic>Molecular electronics</topic><topic>Nonlinearity</topic><topic>Optical properties</topic><topic>Palladium</topic><topic>Polymers</topic><topic>redox properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moorlag, Carolyn</creatorcontrib><creatorcontrib>Clot, Olivier</creatorcontrib><creatorcontrib>Zhu, Yongbao</creatorcontrib><creatorcontrib>Wolf, Michael O.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moorlag, Carolyn</au><au>Clot, Olivier</au><au>Zhu, Yongbao</au><au>Wolf, Michael O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-containing conjugated oligo- and polythiophenes</atitle><jtitle>Macromolecular symposia.</jtitle><addtitle>Macromol. 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subjects | Backbone conductivity conjugated polymers Electronics electropolymerization Iron metal-containing polymers Molecular electronics Nonlinearity Optical properties Palladium Polymers redox properties |
title | Metal-containing conjugated oligo- and polythiophenes |
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