Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide

Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH)2) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Macromolecular symposia. 2001-06, Vol.170 (1), p.205-212
Hauptverfasser: Liauw, Christopher M., Khunova, Viera, Lees, Graham C., Rothon, Roger N.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 212
container_issue 1
container_start_page 205
container_title Macromolecular symposia.
container_volume 170
creator Liauw, Christopher M.
Khunova, Viera
Lees, Graham C.
Rothon, Roger N.
description Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH)2) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composite. These significant improvements in properties were found (via response surface analysis, DSC and matrix extraction‐DRIFTS studies) to be due to encapsulation of the filler particles with the elastomeric poly(ethene‐co‐propene) impact modifier phase of the IMPP. Acceptable processing characteristics can be realised together with excellent mechanical properties, via judicious addition of a lubricant (a fatty acid amide/ester blend) to the formulation.
doi_str_mv 10.1002/1521-3900(200106)170:1<205::AID-MASY205>3.0.CO;2-A
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1266737638</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1266737638</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2935-ba3a32b03522560e08df5535e2af760c0b77fe9267238d1a97e3e1c2f984a2ce3</originalsourceid><addsrcrecordid>eNqVkU1vEzEQhlcIJErhP_iYSmw6tuvdbEBIS_qRSCmp-Ko4jRzvLDHsV-1NSw789zraticunOyx3nk0nieKphzGHEAccyV4LDOAkQDgkBzxFKb8vQA1neaL0_gy__IjFB_kGMaz1TsR58-ig6em5-EOQsRcJvAyeuX9LwDIspQfRH8XTU-u22hPzPdua_qtI1bQLVVtV1PTM9swW3fa9KxuC1taKtjV1fHlz9FqfiSYaeuu9bYnzxyFkA2NO9a51pD3IXpn-w3jb2XcbajZVdQEuK11Rba2Bb2OXpS68vTm4TyMvp2ffZ3N4-XqYjHLl7ERmVTxWkstxRqkEkIlQDApSqWkIqHLNAED6zQtKRNJKuSk4DpLSRI3oswmJ1oYkofRaOCGwW625HusrTdUVbqhduuRiyRJZZrISYh-HqLGtd47KrFzYWC3Qw64d4H7teJ-rTi4wOACeSgUYnCBDy5QIuBshQLzAP0-QO9sRbv_If4b-PgUwPEAtr6nP09g7X7j_kMKrz9dYHK-nGfXJx9Rynv42aqJ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1266737638</pqid></control><display><type>article</type><title>Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide</title><source>Wiley Journals</source><creator>Liauw, Christopher M. ; Khunova, Viera ; Lees, Graham C. ; Rothon, Roger N.</creator><creatorcontrib>Liauw, Christopher M. ; Khunova, Viera ; Lees, Graham C. ; Rothon, Roger N.</creatorcontrib><description>Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH)2) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composite. These significant improvements in properties were found (via response surface analysis, DSC and matrix extraction‐DRIFTS studies) to be due to encapsulation of the filler particles with the elastomeric poly(ethene‐co‐propene) impact modifier phase of the IMPP. Acceptable processing characteristics can be realised together with excellent mechanical properties, via judicious addition of a lubricant (a fatty acid amide/ester blend) to the formulation.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/1521-3900(200106)170:1&lt;205::AID-MASY205&gt;3.0.CO;2-A</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>Esters ; Fatty acids ; Impact modifiers ; Interphase ; Isotactic ; Lubricants ; Polypropylenes ; Response surfaces</subject><ispartof>Macromolecular symposia., 2001-06, Vol.170 (1), p.205-212</ispartof><rights>2001 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F1521-3900%28200106%29170%3A1%3C205%3A%3AAID-MASY205%3E3.0.CO%3B2-A$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F1521-3900%28200106%29170%3A1%3C205%3A%3AAID-MASY205%3E3.0.CO%3B2-A$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Liauw, Christopher M.</creatorcontrib><creatorcontrib>Khunova, Viera</creatorcontrib><creatorcontrib>Lees, Graham C.</creatorcontrib><creatorcontrib>Rothon, Roger N.</creatorcontrib><title>Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide</title><title>Macromolecular symposia.</title><addtitle>Macromol. Symp</addtitle><description>Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH)2) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composite. These significant improvements in properties were found (via response surface analysis, DSC and matrix extraction‐DRIFTS studies) to be due to encapsulation of the filler particles with the elastomeric poly(ethene‐co‐propene) impact modifier phase of the IMPP. Acceptable processing characteristics can be realised together with excellent mechanical properties, via judicious addition of a lubricant (a fatty acid amide/ester blend) to the formulation.</description><subject>Esters</subject><subject>Fatty acids</subject><subject>Impact modifiers</subject><subject>Interphase</subject><subject>Isotactic</subject><subject>Lubricants</subject><subject>Polypropylenes</subject><subject>Response surfaces</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqVkU1vEzEQhlcIJErhP_iYSmw6tuvdbEBIS_qRSCmp-Ko4jRzvLDHsV-1NSw789zraticunOyx3nk0nieKphzGHEAccyV4LDOAkQDgkBzxFKb8vQA1neaL0_gy__IjFB_kGMaz1TsR58-ig6em5-EOQsRcJvAyeuX9LwDIspQfRH8XTU-u22hPzPdua_qtI1bQLVVtV1PTM9swW3fa9KxuC1taKtjV1fHlz9FqfiSYaeuu9bYnzxyFkA2NO9a51pD3IXpn-w3jb2XcbajZVdQEuK11Rba2Bb2OXpS68vTm4TyMvp2ffZ3N4-XqYjHLl7ERmVTxWkstxRqkEkIlQDApSqWkIqHLNAED6zQtKRNJKuSk4DpLSRI3oswmJ1oYkofRaOCGwW625HusrTdUVbqhduuRiyRJZZrISYh-HqLGtd47KrFzYWC3Qw64d4H7teJ-rTi4wOACeSgUYnCBDy5QIuBshQLzAP0-QO9sRbv_If4b-PgUwPEAtr6nP09g7X7j_kMKrz9dYHK-nGfXJx9Rynv42aqJ</recordid><startdate>200106</startdate><enddate>200106</enddate><creator>Liauw, Christopher M.</creator><creator>Khunova, Viera</creator><creator>Lees, Graham C.</creator><creator>Rothon, Roger N.</creator><general>WILEY-VCH Verlag GmbH</general><general>WILEY‐VCH Verlag GmbH</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200106</creationdate><title>Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide</title><author>Liauw, Christopher M. ; Khunova, Viera ; Lees, Graham C. ; Rothon, Roger N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2935-ba3a32b03522560e08df5535e2af760c0b77fe9267238d1a97e3e1c2f984a2ce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Esters</topic><topic>Fatty acids</topic><topic>Impact modifiers</topic><topic>Interphase</topic><topic>Isotactic</topic><topic>Lubricants</topic><topic>Polypropylenes</topic><topic>Response surfaces</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liauw, Christopher M.</creatorcontrib><creatorcontrib>Khunova, Viera</creatorcontrib><creatorcontrib>Lees, Graham C.</creatorcontrib><creatorcontrib>Rothon, Roger N.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liauw, Christopher M.</au><au>Khunova, Viera</au><au>Lees, Graham C.</au><au>Rothon, Roger N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide</atitle><jtitle>Macromolecular symposia.</jtitle><addtitle>Macromol. Symp</addtitle><date>2001-06</date><risdate>2001</risdate><volume>170</volume><issue>1</issue><spage>205</spage><epage>212</epage><pages>205-212</pages><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>Interphase modification of impact modified isotactic poly(propene) (IMPP)/magnesium hydroxide (Mg(OH)2) composites, via use of the reactive modifier 1,3 phenylene dimaleimide (BMI) has led to the formation of composites that have strength and toughness more than twice that of the unmodified composite. These significant improvements in properties were found (via response surface analysis, DSC and matrix extraction‐DRIFTS studies) to be due to encapsulation of the filler particles with the elastomeric poly(ethene‐co‐propene) impact modifier phase of the IMPP. Acceptable processing characteristics can be realised together with excellent mechanical properties, via judicious addition of a lubricant (a fatty acid amide/ester blend) to the formulation.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><doi>10.1002/1521-3900(200106)170:1&lt;205::AID-MASY205&gt;3.0.CO;2-A</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1022-1360
ispartof Macromolecular symposia., 2001-06, Vol.170 (1), p.205-212
issn 1022-1360
1521-3900
language eng
recordid cdi_proquest_miscellaneous_1266737638
source Wiley Journals
subjects Esters
Fatty acids
Impact modifiers
Interphase
Isotactic
Lubricants
Polypropylenes
Response surfaces
title Interphase structure development in impact modified PP/Mg(OH)2 composites reactively processed with 1,3-phenylene dimaleimide
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T22%3A51%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Interphase%20structure%20development%20in%20impact%20modified%20PP/Mg(OH)2%20composites%20reactively%20processed%20with%201,3-phenylene%20dimaleimide&rft.jtitle=Macromolecular%20symposia.&rft.au=Liauw,%20Christopher%20M.&rft.date=2001-06&rft.volume=170&rft.issue=1&rft.spage=205&rft.epage=212&rft.pages=205-212&rft.issn=1022-1360&rft.eissn=1521-3900&rft_id=info:doi/10.1002/1521-3900(200106)170:1%3C205::AID-MASY205%3E3.0.CO;2-A&rft_dat=%3Cproquest_cross%3E1266737638%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1266737638&rft_id=info:pmid/&rfr_iscdi=true