Dissipation Kinetics of Chlorantraniliprole in Soils of Sugarcane Ecosystem
Dissipation kinetics of chlorantraniliprole was studied in sandy loam soils of sugarcane ecosystem by adopting a rapid analytical method. The recovery of chlorantraniliprole was 91.67 % when extracted with ethyl acetate as against only 65.58 % in acetonitrile-based extraction. An additional cleanup...
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| Veröffentlicht in: | Bulletin of environmental contamination and toxicology 2012-12, Vol.89 (6), p.1268-1271 |
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| container_title | Bulletin of environmental contamination and toxicology |
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| creator | Ramasubramanian, Thirumalaiandi Paramasivam, Mariappan Salin, Kallolathu Purushothaman Jayanthi, Ramabhadran |
| description | Dissipation kinetics of chlorantraniliprole was studied in sandy loam soils of sugarcane ecosystem by adopting a rapid analytical method. The recovery of chlorantraniliprole was 91.67 % when extracted with ethyl acetate as against only 65.58 % in acetonitrile-based extraction. An additional cleanup step with primary secondary amine did not enhance the recovery significantly over the no-cleanup method. The ethyl acetate-based extraction followed by direct quantification in HPLC (High-performance liquid chromatography) without any cleanup facilitated rapid quantification of chlorantraniliprole residues. The LOQ (limit of quantification) of the method was 0.01 μg/g. The half-life of chlorantraniliprole was 6.50 and 6.81 days for the recommended and double the recommended doses, respectively. |
| doi_str_mv | 10.1007/s00128-012-0855-9 |
| format | Article |
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The recovery of chlorantraniliprole was 91.67 % when extracted with ethyl acetate as against only 65.58 % in acetonitrile-based extraction. An additional cleanup step with primary secondary amine did not enhance the recovery significantly over the no-cleanup method. The ethyl acetate-based extraction followed by direct quantification in HPLC (High-performance liquid chromatography) without any cleanup facilitated rapid quantification of chlorantraniliprole residues. The LOQ (limit of quantification) of the method was 0.01 μg/g. The half-life of chlorantraniliprole was 6.50 and 6.81 days for the recommended and double the recommended doses, respectively.</description><identifier>ISSN: 0007-4861</identifier><identifier>EISSN: 1432-0800</identifier><identifier>DOI: 10.1007/s00128-012-0855-9</identifier><identifier>PMID: 23064445</identifier><language>eng</language><publisher>New York: Springer-Verlag</publisher><subject>Acetic acid ; Aquatic Pollution ; Earth and Environmental Science ; Ecosystem ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental Monitoring ; Half-Life ; Insecticides ; Insecticides - analysis ; Insecticides - chemistry ; Kinetics ; Liquid chromatography ; Models, Chemical ; ortho-Aminobenzoates - analysis ; ortho-Aminobenzoates - chemistry ; Pesticide Residues - analysis ; Pesticide Residues - chemistry ; Pollution ; Saccharum ; Sandy loam ; Sandy soils ; Soil - chemistry ; Soil contaminants ; Soil Pollutants - analysis ; Soil Pollutants - chemistry ; Soil Science & Conservation ; Sugarcane ; Terrestrial ecosystems ; Waste Water Technology ; Water Management ; Water Pollution Control</subject><ispartof>Bulletin of environmental contamination and toxicology, 2012-12, Vol.89 (6), p.1268-1271</ispartof><rights>Springer Science+Business Media New York 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-8e4120029f52d1ba2653a6d6726c658280e9a81ee3723fe0f61128206534e6423</citedby><cites>FETCH-LOGICAL-c405t-8e4120029f52d1ba2653a6d6726c658280e9a81ee3723fe0f61128206534e6423</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00128-012-0855-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00128-012-0855-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23064445$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramasubramanian, Thirumalaiandi</creatorcontrib><creatorcontrib>Paramasivam, Mariappan</creatorcontrib><creatorcontrib>Salin, Kallolathu Purushothaman</creatorcontrib><creatorcontrib>Jayanthi, Ramabhadran</creatorcontrib><title>Dissipation Kinetics of Chlorantraniliprole in Soils of Sugarcane Ecosystem</title><title>Bulletin of environmental contamination and toxicology</title><addtitle>Bull Environ Contam Toxicol</addtitle><addtitle>Bull Environ Contam Toxicol</addtitle><description>Dissipation kinetics of chlorantraniliprole was studied in sandy loam soils of sugarcane ecosystem by adopting a rapid analytical method. The recovery of chlorantraniliprole was 91.67 % when extracted with ethyl acetate as against only 65.58 % in acetonitrile-based extraction. An additional cleanup step with primary secondary amine did not enhance the recovery significantly over the no-cleanup method. The ethyl acetate-based extraction followed by direct quantification in HPLC (High-performance liquid chromatography) without any cleanup facilitated rapid quantification of chlorantraniliprole residues. The LOQ (limit of quantification) of the method was 0.01 μg/g. The half-life of chlorantraniliprole was 6.50 and 6.81 days for the recommended and double the recommended doses, respectively.</description><subject>Acetic acid</subject><subject>Aquatic Pollution</subject><subject>Earth and Environmental Science</subject><subject>Ecosystem</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental Monitoring</subject><subject>Half-Life</subject><subject>Insecticides</subject><subject>Insecticides - analysis</subject><subject>Insecticides - chemistry</subject><subject>Kinetics</subject><subject>Liquid chromatography</subject><subject>Models, Chemical</subject><subject>ortho-Aminobenzoates - analysis</subject><subject>ortho-Aminobenzoates - chemistry</subject><subject>Pesticide Residues - analysis</subject><subject>Pesticide Residues - chemistry</subject><subject>Pollution</subject><subject>Saccharum</subject><subject>Sandy loam</subject><subject>Sandy soils</subject><subject>Soil - chemistry</subject><subject>Soil contaminants</subject><subject>Soil Pollutants - analysis</subject><subject>Soil Pollutants - chemistry</subject><subject>Soil Science & Conservation</subject><subject>Sugarcane</subject><subject>Terrestrial ecosystems</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0007-4861</issn><issn>1432-0800</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkT9PwzAQxS0EoqXwAVhQJBaWwNmxnWREpfxRKzEUZstNneIqjYudDP32XEhBCAkx-Czrfvf8To-QcwrXFCC9CQCUZTGWGDIh4vyADClPuhfAIRkCQjHPJB2QkxDWSIuMsWMyYAlIzrkYkumdDcFudWNdHU1tbRpbhMiV0fitcl7XDR5b2a13lYlsHc2drT7783alfaFrE00KF3ahMZtTclTqKpiz_T0ir_eTl_FjPHt-eBrfzuKCg2jizHDKAFheCrakC82kSLRcypTJQqLBDEyuM2pMkrKkNFBKilsyQIwbyVkyIle9Lrp6b01o1MaGwlQVunFtUJSJNJU0Z_R_lAoKCUNfiF7-Qteu9TUughSHnOciyZGiPVV4F4I3pdp6u9F-pyioLhTVh6KwqC4U1c1c7JXbxcYsvye-UkCA9UDAVr0y_sfXf6p-AI7qlAc</recordid><startdate>20121201</startdate><enddate>20121201</enddate><creator>Ramasubramanian, Thirumalaiandi</creator><creator>Paramasivam, Mariappan</creator><creator>Salin, Kallolathu Purushothaman</creator><creator>Jayanthi, Ramabhadran</creator><general>Springer-Verlag</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7T7</scope><scope>7TK</scope><scope>7TV</scope><scope>7U7</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>88I</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>P64</scope><scope>PATMY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope><scope>7ST</scope><scope>7T2</scope><scope>7U2</scope><scope>SOI</scope></search><sort><creationdate>20121201</creationdate><title>Dissipation Kinetics of Chlorantraniliprole in Soils of Sugarcane Ecosystem</title><author>Ramasubramanian, Thirumalaiandi ; Paramasivam, Mariappan ; Salin, Kallolathu Purushothaman ; Jayanthi, Ramabhadran</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-8e4120029f52d1ba2653a6d6726c658280e9a81ee3723fe0f61128206534e6423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Acetic acid</topic><topic>Aquatic Pollution</topic><topic>Earth and Environmental Science</topic><topic>Ecosystem</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental Monitoring</topic><topic>Half-Life</topic><topic>Insecticides</topic><topic>Insecticides - analysis</topic><topic>Insecticides - chemistry</topic><topic>Kinetics</topic><topic>Liquid chromatography</topic><topic>Models, Chemical</topic><topic>ortho-Aminobenzoates - analysis</topic><topic>ortho-Aminobenzoates - chemistry</topic><topic>Pesticide Residues - analysis</topic><topic>Pesticide Residues - chemistry</topic><topic>Pollution</topic><topic>Saccharum</topic><topic>Sandy loam</topic><topic>Sandy soils</topic><topic>Soil - chemistry</topic><topic>Soil contaminants</topic><topic>Soil Pollutants - analysis</topic><topic>Soil Pollutants - chemistry</topic><topic>Soil Science & Conservation</topic><topic>Sugarcane</topic><topic>Terrestrial ecosystems</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramasubramanian, Thirumalaiandi</creatorcontrib><creatorcontrib>Paramasivam, Mariappan</creatorcontrib><creatorcontrib>Salin, Kallolathu Purushothaman</creatorcontrib><creatorcontrib>Jayanthi, Ramabhadran</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Neurosciences Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Safety Science and Risk</collection><collection>Environment Abstracts</collection><jtitle>Bulletin of environmental contamination and toxicology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramasubramanian, Thirumalaiandi</au><au>Paramasivam, Mariappan</au><au>Salin, Kallolathu Purushothaman</au><au>Jayanthi, Ramabhadran</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dissipation Kinetics of Chlorantraniliprole in Soils of Sugarcane Ecosystem</atitle><jtitle>Bulletin of environmental contamination and toxicology</jtitle><stitle>Bull Environ Contam Toxicol</stitle><addtitle>Bull Environ Contam Toxicol</addtitle><date>2012-12-01</date><risdate>2012</risdate><volume>89</volume><issue>6</issue><spage>1268</spage><epage>1271</epage><pages>1268-1271</pages><issn>0007-4861</issn><eissn>1432-0800</eissn><abstract>Dissipation kinetics of chlorantraniliprole was studied in sandy loam soils of sugarcane ecosystem by adopting a rapid analytical method. The recovery of chlorantraniliprole was 91.67 % when extracted with ethyl acetate as against only 65.58 % in acetonitrile-based extraction. An additional cleanup step with primary secondary amine did not enhance the recovery significantly over the no-cleanup method. The ethyl acetate-based extraction followed by direct quantification in HPLC (High-performance liquid chromatography) without any cleanup facilitated rapid quantification of chlorantraniliprole residues. The LOQ (limit of quantification) of the method was 0.01 μg/g. The half-life of chlorantraniliprole was 6.50 and 6.81 days for the recommended and double the recommended doses, respectively.</abstract><cop>New York</cop><pub>Springer-Verlag</pub><pmid>23064445</pmid><doi>10.1007/s00128-012-0855-9</doi><tpages>4</tpages></addata></record> |
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| subjects | Acetic acid Aquatic Pollution Earth and Environmental Science Ecosystem Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental Monitoring Half-Life Insecticides Insecticides - analysis Insecticides - chemistry Kinetics Liquid chromatography Models, Chemical ortho-Aminobenzoates - analysis ortho-Aminobenzoates - chemistry Pesticide Residues - analysis Pesticide Residues - chemistry Pollution Saccharum Sandy loam Sandy soils Soil - chemistry Soil contaminants Soil Pollutants - analysis Soil Pollutants - chemistry Soil Science & Conservation Sugarcane Terrestrial ecosystems Waste Water Technology Water Management Water Pollution Control |
| title | Dissipation Kinetics of Chlorantraniliprole in Soils of Sugarcane Ecosystem |
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