A mechanistic study on the Hooker oxidation: synthesis of novel indane carboxylic acid derivatives from lapachol

The Hooker oxidation is one of the most intriguing transformations wherein lapachol (1) is readily converted to norlapachol (2) in very good yield. This one-pot reaction involves a very intricate mechanism in which the alkyl side chain of lapachol is shortened by one carbon unit. Previous studies ha...

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Veröffentlicht in:	Organic & biomolecular chemistry 2013-01, Vol.11 (3), p.459-468
Hauptverfasser:	Eyong, Kenneth O, Puppala, Manohar, Kumar, Ponminor Senthil, Lamshöft, Marc, Folefoc, Gabriel N, Spiteller, Michael, Baskaran, Sundarababu
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic Acids - chemical synthesis Carboxylic Acids - chemistry Indans - chemical synthesis Indans - chemistry Models, Molecular Molecular Structure Naphthoquinones - chemistry Oxidation-Reduction
Online-Zugang:	Volltext
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