Photoisomerisation in single molecules of nitroprusside embedded in mesopores of xerogels

Photoswitchable hybrid materials are successfully prepared by embedding guanidinium nitroprussides (GuNP, (CN 3 H 6 ) 2 [Fe(CN) 5 NO]) into mesopores of transparent xerogel monoliths. The such prepared hybrid materials exhibit a higher photostability than the corresponding GuNP solutions, whereby th...

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Veröffentlicht in:	Journal of sol-gel science and technology 2009-06, Vol.50 (3), p.403-408
Hauptverfasser:	Schuy, Andrea, Woike, Theo, Schaniel, Dominik
Format:	Artikel
Sprache:	eng
Schlagworte:	Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Embedding Exact sciences and technology General and physical chemistry Glass Inorganic Chemistry Iron Isomers Ligands Materials Science Nanotechnology Natural Materials Nitrosyls Optical and Electronic Materials Organic chemistry Original Paper Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Porous materials Silicon dioxide Spectra Titanium dioxide Vibration Xerogels
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