A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of an NHC-Rh hydrosilylation catalyst

Coupling of a histidinium salt with a MetAlaAla amino acid sequence followed by metallation with [RhCl(cod)](2) yields a rhodium(I) NHC complex with a pending peptide residue. Methionine chelation, induced by chloride abstraction from the metal coordination sphere, affords an efficient hydrosilylati...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-11, Vol.48 (89), p.10960-10962
Hauptverfasser:	Monney, Angèle, Albrecht, Martin
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino acids Biochemistry Catalysis Catalysts Chelating Chelating Agents - chemical synthesis Chelating Agents - chemistry Chelation Heterocyclic Compounds - chemistry Histidine - chemistry Hydrosilylation Methane - analogs & derivatives Methane - chemistry Molecular Structure Residues Rhodium Rhodium - chemistry Silanes - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!