Block Copolymer Orientation Control Using a Top-Coat Surface Treatment

Directed self-assembly of Si containing block copolymers (BCP) is a candidate for next generation patterning technology because it enables both high resolution and high etch contrast. Achieving high resolution requires a high χ parameter. However, it is often difficult to achieve perpendicular patte...

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Veröffentlicht in:Journal of Photopolymer Science and Technology 2012/06/26, Vol.25(1), pp.125-130
Hauptverfasser: Seshimo, Takehiro, Bates, Christopher M., Dean, Leon M., Cushen, Julia D., Durand, William J., Maher, Michael J., Ellison, Christopher J., Willson, C. Grant
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container_end_page 130
container_issue 1
container_start_page 125
container_title Journal of Photopolymer Science and Technology
container_volume 25
creator Seshimo, Takehiro
Bates, Christopher M.
Dean, Leon M.
Cushen, Julia D.
Durand, William J.
Maher, Michael J.
Ellison, Christopher J.
Willson, C. Grant
description Directed self-assembly of Si containing block copolymers (BCP) is a candidate for next generation patterning technology because it enables both high resolution and high etch contrast. Achieving high resolution requires a high χ parameter. However, it is often difficult to achieve perpendicular patterns by thermal annealing of BCPs with a lower surface energy block, which tends to align with the air interface. New top surface treatment materials that provide a surface energy between those of the blocks have been developed that enable perpendicular pattern alignment with block copolymers that have a low surface energy block.
doi_str_mv 10.2494/photopolymer.25.125
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1349-6336
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source J-STAGE Free; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry
subjects Alignment
Block copolymers
Blocking
directed self assembly
High resolution
Patterning
Self assembly
Si-containing block copolymer
Surface energy
Surface treatment
Top-coat
title Block Copolymer Orientation Control Using a Top-Coat Surface Treatment
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