Experimental determination of thermodynamic characteristics of smithsonite
► Heat capacity of natural smithonite was measured by means of adiabatic calorimetry. ► The experimental data were processed using spline-approximation to obtain Cp (298.15). ► Thermodynamic functions of smithonite were calculated in the range of (4 to 320)K. The heat capacity of natural zinc carbon...
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| Veröffentlicht in: | The Journal of chemical thermodynamics 2012-08, Vol.51, p.31-36 |
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| container_title | The Journal of chemical thermodynamics |
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| creator | Bissengaliyeva, М.R. Gogol, D.B. Taimassova, Sh.T. Bekturganov, N.S. |
| description | ► Heat capacity of natural smithonite was measured by means of adiabatic calorimetry. ► The experimental data were processed using spline-approximation to obtain Cp (298.15). ► Thermodynamic functions of smithonite were calculated in the range of (4 to 320)K.
The heat capacity of natural zinc carbonate (smithsonite, ZnCO3) has been measured by the method of low-temperature adiabatic calorimetry over the temperature range of (4.4 to 320)K. Its thermodynamic functions have been calculated based on the experimental data on the heat capacity. The standard values of the heat capacity and entropy for smithsonite are as follows: Cp,m=80.36±0.09J·mol−1·K−1, Sm=81.28±0.09J·mol−1·K−1. |
| doi_str_mv | 10.1016/j.jct.2012.02.028 |
| format | Article |
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The heat capacity of natural zinc carbonate (smithsonite, ZnCO3) has been measured by the method of low-temperature adiabatic calorimetry over the temperature range of (4.4 to 320)K. Its thermodynamic functions have been calculated based on the experimental data on the heat capacity. The standard values of the heat capacity and entropy for smithsonite are as follows: Cp,m=80.36±0.09J·mol−1·K−1, Sm=81.28±0.09J·mol−1·K−1.</description><identifier>ISSN: 0021-9614</identifier><identifier>EISSN: 1096-3626</identifier><identifier>DOI: 10.1016/j.jct.2012.02.028</identifier><identifier>CODEN: JCTDAF</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Adiabatic calorimetry ; Chemical thermodynamics ; Chemistry ; Entropy ; Exact sciences and technology ; General and physical chemistry ; General. Theory ; Heat capacity ; Mathematical analysis ; Natural minerals ; Specific heat ; Thermodynamic functions ; Thermodynamics ; Zinc ; Zinc ores</subject><ispartof>The Journal of chemical thermodynamics, 2012-08, Vol.51, p.31-36</ispartof><rights>2012 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-bb4fffd42ab50b22336f5cc015c01eee03c90ae84d6a9afcb764f793891cbf023</citedby><cites>FETCH-LOGICAL-c360t-bb4fffd42ab50b22336f5cc015c01eee03c90ae84d6a9afcb764f793891cbf023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jct.2012.02.028$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25868120$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bissengaliyeva, М.R.</creatorcontrib><creatorcontrib>Gogol, D.B.</creatorcontrib><creatorcontrib>Taimassova, Sh.T.</creatorcontrib><creatorcontrib>Bekturganov, N.S.</creatorcontrib><title>Experimental determination of thermodynamic characteristics of smithsonite</title><title>The Journal of chemical thermodynamics</title><description>► Heat capacity of natural smithonite was measured by means of adiabatic calorimetry. ► The experimental data were processed using spline-approximation to obtain Cp (298.15). ► Thermodynamic functions of smithonite were calculated in the range of (4 to 320)K.
The heat capacity of natural zinc carbonate (smithsonite, ZnCO3) has been measured by the method of low-temperature adiabatic calorimetry over the temperature range of (4.4 to 320)K. Its thermodynamic functions have been calculated based on the experimental data on the heat capacity. The standard values of the heat capacity and entropy for smithsonite are as follows: Cp,m=80.36±0.09J·mol−1·K−1, Sm=81.28±0.09J·mol−1·K−1.</description><subject>Adiabatic calorimetry</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Entropy</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>General. Theory</subject><subject>Heat capacity</subject><subject>Mathematical analysis</subject><subject>Natural minerals</subject><subject>Specific heat</subject><subject>Thermodynamic functions</subject><subject>Thermodynamics</subject><subject>Zinc</subject><subject>Zinc ores</subject><issn>0021-9614</issn><issn>1096-3626</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWD9-gLdeBC9bJ8luusGTiJ8UvOg5ZGcnNGU_apKK_nuzVDwKMwwDz7zD-zJ2wWHBgavrzWKDaSGAiwVMVR-wGQetCqmEOmQzAMELrXh5zE5i3ACAlhpm7OX-a0vB9zQk281bShR6P9jkx2E-unla531svwfbe5zj2gaLGfExeYwTEHuf1nEcfKIzduRsF-n8d56y94f7t7unYvX6-Hx3uypQKkhF05TOubYUtqmgEUJK5SpE4FVuIgKJGizVZaustg6bpSrdUstac2wcCHnKrva62zB-7Cgm0_uI1HV2oHEXDReC10rqqswo36MYxhgDObPNXm34NhzMlJvZmJybmXIzMFWdby5_5W1E27lgB_Tx71BUtaq5gMzd7DnKXj89BRPR04DU-kBZsx39P19-AH9ChJ8</recordid><startdate>20120801</startdate><enddate>20120801</enddate><creator>Bissengaliyeva, М.R.</creator><creator>Gogol, D.B.</creator><creator>Taimassova, Sh.T.</creator><creator>Bekturganov, N.S.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120801</creationdate><title>Experimental determination of thermodynamic characteristics of smithsonite</title><author>Bissengaliyeva, М.R. ; Gogol, D.B. ; Taimassova, Sh.T. ; Bekturganov, N.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-bb4fffd42ab50b22336f5cc015c01eee03c90ae84d6a9afcb764f793891cbf023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Adiabatic calorimetry</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Entropy</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>General. Theory</topic><topic>Heat capacity</topic><topic>Mathematical analysis</topic><topic>Natural minerals</topic><topic>Specific heat</topic><topic>Thermodynamic functions</topic><topic>Thermodynamics</topic><topic>Zinc</topic><topic>Zinc ores</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bissengaliyeva, М.R.</creatorcontrib><creatorcontrib>Gogol, D.B.</creatorcontrib><creatorcontrib>Taimassova, Sh.T.</creatorcontrib><creatorcontrib>Bekturganov, N.S.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>The Journal of chemical thermodynamics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bissengaliyeva, М.R.</au><au>Gogol, D.B.</au><au>Taimassova, Sh.T.</au><au>Bekturganov, N.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental determination of thermodynamic characteristics of smithsonite</atitle><jtitle>The Journal of chemical thermodynamics</jtitle><date>2012-08-01</date><risdate>2012</risdate><volume>51</volume><spage>31</spage><epage>36</epage><pages>31-36</pages><issn>0021-9614</issn><eissn>1096-3626</eissn><coden>JCTDAF</coden><abstract>► Heat capacity of natural smithonite was measured by means of adiabatic calorimetry. ► The experimental data were processed using spline-approximation to obtain Cp (298.15). ► Thermodynamic functions of smithonite were calculated in the range of (4 to 320)K.
The heat capacity of natural zinc carbonate (smithsonite, ZnCO3) has been measured by the method of low-temperature adiabatic calorimetry over the temperature range of (4.4 to 320)K. Its thermodynamic functions have been calculated based on the experimental data on the heat capacity. The standard values of the heat capacity and entropy for smithsonite are as follows: Cp,m=80.36±0.09J·mol−1·K−1, Sm=81.28±0.09J·mol−1·K−1.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jct.2012.02.028</doi><tpages>6</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Adiabatic calorimetry Chemical thermodynamics Chemistry Entropy Exact sciences and technology General and physical chemistry General. Theory Heat capacity Mathematical analysis Natural minerals Specific heat Thermodynamic functions Thermodynamics Zinc Zinc ores |
| title | Experimental determination of thermodynamic characteristics of smithsonite |
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