Surfactant-Free Hydrothermal Synthesis of Ag/C Nanocables

A facile method is described here on synthesis of high-aspect-ratio Ag/C core/sheath nanocables via a hydrothermal process in the presence of Ag2 S and in the absence of any surfactant or polymers. We demonstrate that glucose can act as a reducing reagent and provide carbon source to form a core-she...

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Veröffentlicht in:Materials express 2012-06, Vol.2 (2), p.130-136
Hauptverfasser: Mu, Jianlin, Liu, Ying, Wang, Hui, Ye, Jinwen, Wen, Xiaogang, Gu, Lin, Xie, Yu-Tao
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container_issue 2
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container_title Materials express
container_volume 2
creator Mu, Jianlin
Liu, Ying
Wang, Hui
Ye, Jinwen
Wen, Xiaogang
Gu, Lin
Xie, Yu-Tao
description A facile method is described here on synthesis of high-aspect-ratio Ag/C core/sheath nanocables via a hydrothermal process in the presence of Ag2 S and in the absence of any surfactant or polymers. We demonstrate that glucose can act as a reducing reagent and provide carbon source to form a core-shell structure. The S2- ion plays an important role in controlling the Ag+ concentration and then the anisotropic growth of nanocables, and at the same time, the uncoated Ag particles get eroded and reused via Ag2 S intermediate. The formation of 1D Ag nanowire inner core is attributed mainly to the low growth rate of Ag nanocrystalline nuclei and the later carboncoating protection.
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subjects Carbon
Core/sheath
Glucose
Mechanism
Nanocable
Nanocomposites
Nanomaterials
Nanostructure
Polymers
Silver
Silver/carbon
Synthesis
title Surfactant-Free Hydrothermal Synthesis of Ag/C Nanocables
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