Free Base and Metal Complexes of 5,15-Diaza-10,20-dimesitylporphyrins: Synthesis, Structures, Optical and Electrochemical Properties, and Aromaticities

The synthesis, structures, optical and electrochemical properties, and aromaticity of a series of 5,15-diaza-10,20-dimesitylporphyrins (M–DAP; M = Pb, H2, Ni, Pd, Pt, Zn; mesityl = 2,4,6-trimethylphenyl) are reported. Treatment of mesityl-substituted bis­(5,5′-dibromodipyrrin) with sodium azide in t...

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Veröffentlicht in:	Inorganic chemistry 2012-12, Vol.51 (23), p.12879-12890
Hauptverfasser:	Matano, Yoshihiro, Shibano, Tarou, Nakano, Haruyuki, Kimura, Yoshifumi, Imahori, Hiroshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Electrochemical Techniques Models, Molecular Molecular Structure Optical Phenomena Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Platinum - chemistry Porphyrins - chemistry Stereoisomerism Zinc - chemistry
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