Studying the Kinetics of Crystalline Silicon Nanoparticle Lithiation with In Situ Transmission Electron Microscopy

In situ transmission electron microscopy (TEM) is used to study the electrochemical lithiation of high‐capacity crystalline Si nanoparticles for use in Li‐ion battery anodes. The lithiation reaction slows down as it progresses into the particle interior, and analysis suggests that this behavior is d...

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Veröffentlicht in:	Advanced Materials, 24(45):6034-6041 24(45):6034-6041, 2012-11, Vol.24 (45), p.6034-6041
Hauptverfasser:	McDowell, Matthew T., Ryu, Ill, Lee, Seok Woo, Wang, Chongmin, Nix, William D., Cui, Yi
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystal structure Crystallinity Crystallization - methods Diffusion Electrons energy storage Environmental Molecular Sciences Laboratory in situ TEM Kinetics Li-ion batteries Lithium - chemistry Lithium - isolation & purification Lithium-ion batteries Materials science Materials Testing Microscopy, Electron, Transmission Nanoparticles Nanoparticles - chemistry Nanoparticles - ultrastructure Particle Size phase transformations Silicon Silicon - chemistry Transmission electron microscopy
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