Influence of the Solvent and the Enantiomeric Purity on the Transition between Different Supramolecular Polymers

The self‐assembly of two enantiomerically pure hexa(oligo (p‐phenylene vinylene))‐substituted benzenes having 24 stereocenters was studied in pure methylcyclohexane (MCH) and in a mixture of MCH/toluene (4:1). Irrespective of the solvent a cooperative supramolecular polymerization mechanism was dete...

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Veröffentlicht in:	Chemistry : a European journal 2012-11, Vol.18 (47), p.15057-15064
Hauptverfasser:	Wolffs, Martin, van Velthoven, Juliën L. J., Lou, Xianwen, Bovee, Ralf A. A., Pouderoijen, Maarten, van Dongen, Joost L. J., Schenning, Albertus P. H. J., Meijer, E. W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chromatography cooperative effects Macromolecular Substances - chemical synthesis Macromolecular Substances - chemistry majority rules Molecular Structure Polymerization Polymers - chemical synthesis Polymers - chemistry self-assembly size exclusion chromatography Solvents - chemistry Stereoisomerism supramolecular chemistry Thermodynamics
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