Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography–mass spectrometry: Determination of 88 pesticides in berries using SPE and GC–MS
► The focus is simultaneous determination of 88 pesticides in berry with SPE-GC-MS. ► It is a rapid and reliable method that we have developed to analyze 88 pesticides. ► It is the first time to analyze 88 pesticide residues in raspberry and blueberry. A method using solid phase extraction (SPE) cle...
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| Veröffentlicht in: | Food chemistry 2011-07, Vol.127 (2), p.855-865 |
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| creator | Yang, X. Zhang, H. Liu, Y. Wang, J. Zhang, Y.C. Dong, A.J. Zhao, H.T. Sun, C.H. Cui, J. |
| description | ► The focus is simultaneous determination of 88 pesticides in berry with SPE-GC-MS. ► It is a rapid and reliable method that we have developed to analyze 88 pesticides. ► It is the first time to analyze 88 pesticide residues in raspberry and blueberry.
A method using solid phase extraction (SPE) cleanup followed by gas chromatography–mass spectrometry (GC–MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC–MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile–toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2⩾0.99. At the low, medium and high three fortification levels of 0.05–0.5mgkg−1, recoveries fell within 63–137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006–0.05mgkg−1) and quantification (0.02–0.15mgkg−1) were readily achieved with this method for all tested pesticides. |
| doi_str_mv | 10.1016/j.foodchem.2011.01.024 |
| format | Article |
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A method using solid phase extraction (SPE) cleanup followed by gas chromatography–mass spectrometry (GC–MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC–MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile–toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2⩾0.99. At the low, medium and high three fortification levels of 0.05–0.5mgkg−1, recoveries fell within 63–137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006–0.05mgkg−1) and quantification (0.02–0.15mgkg−1) were readily achieved with this method for all tested pesticides.</description><identifier>ISSN: 0308-8146</identifier><identifier>EISSN: 1873-7072</identifier><identifier>DOI: 10.1016/j.foodchem.2011.01.024</identifier><identifier>PMID: 23140746</identifier><identifier>CODEN: FOCHDJ</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Berry fruits ; Biological and medical sciences ; Food industries ; Fruit and vegetable industries ; Fundamental and applied biological sciences. Psychology ; GC–MS ; Multi-residue analysis ; Pesticides ; SPE ; Validation</subject><ispartof>Food chemistry, 2011-07, Vol.127 (2), p.855-865</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2011 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-bc5e556a7b80a182a73b005146edc962345807c1bb7096a65ae452dadd81b8593</citedby><cites>FETCH-LOGICAL-c422t-bc5e556a7b80a182a73b005146edc962345807c1bb7096a65ae452dadd81b8593</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0308814611000823$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23923257$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23140746$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, X.</creatorcontrib><creatorcontrib>Zhang, H.</creatorcontrib><creatorcontrib>Liu, Y.</creatorcontrib><creatorcontrib>Wang, J.</creatorcontrib><creatorcontrib>Zhang, Y.C.</creatorcontrib><creatorcontrib>Dong, A.J.</creatorcontrib><creatorcontrib>Zhao, H.T.</creatorcontrib><creatorcontrib>Sun, C.H.</creatorcontrib><creatorcontrib>Cui, J.</creatorcontrib><title>Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography–mass spectrometry: Determination of 88 pesticides in berries using SPE and GC–MS</title><title>Food chemistry</title><addtitle>Food Chem</addtitle><description>► The focus is simultaneous determination of 88 pesticides in berry with SPE-GC-MS. ► It is a rapid and reliable method that we have developed to analyze 88 pesticides. ► It is the first time to analyze 88 pesticide residues in raspberry and blueberry.
A method using solid phase extraction (SPE) cleanup followed by gas chromatography–mass spectrometry (GC–MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC–MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile–toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2⩾0.99. At the low, medium and high three fortification levels of 0.05–0.5mgkg−1, recoveries fell within 63–137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006–0.05mgkg−1) and quantification (0.02–0.15mgkg−1) were readily achieved with this method for all tested pesticides.</description><subject>Berry fruits</subject><subject>Biological and medical sciences</subject><subject>Food industries</subject><subject>Fruit and vegetable industries</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>GC–MS</subject><subject>Multi-residue analysis</subject><subject>Pesticides</subject><subject>SPE</subject><subject>Validation</subject><issn>0308-8146</issn><issn>1873-7072</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNks-O0zAQxiMEYsvCKyy-IHFJsZ1_DidWZVmQdgVS2bM1sSeNqyQOtoPojXfgwXgHngR32yJuII3kg3_ffKP5JkkuGF0yyspX22VrrVYdDktOGVvSWDx_kCyYqLK0ohV_mCxoRkUqWF6eJU-831JKIyseJ2c8Yzmt8nKR_Lyd-2AceqNnJAOGzmrSWkc0BnSDGSEYOxLbEiHIhD4YZTR6YkbSoHM70rrZBE9mb8YN8bY3Op068EjwW3Cg7tUwarIBT1Tn7ADBbhxM3e7X9x8DeE_8hCrEDwxu95q8_S9fgyfL9aer-_7Xq9jvdv00edRC7_HZ8T1P7t5dfV69T28-Xn9YXd6kKuc8pI0qsChKqBpBgQkOVdZQWsRVoVZ1ybO8ELRSrGkqWpdQFoB5wTVoLVgjijo7T14e-k7OfpnjfHIwXmHfw4h29pKxgsUU6jqPaHlAlbPeO2zl5MwAbicZlfsw5VaewpT7MCWNxffCi6PH3Ayo_8hO6UXgxREAr6BvHYzK-L-4mme8qCL3_MC1YCVsXGTu1tEpo6zORZHxSLw5EBh39tWgk14ZHBXqeBsqSG3Nv6b9DdVez8w</recordid><startdate>20110715</startdate><enddate>20110715</enddate><creator>Yang, X.</creator><creator>Zhang, H.</creator><creator>Liu, Y.</creator><creator>Wang, J.</creator><creator>Zhang, Y.C.</creator><creator>Dong, A.J.</creator><creator>Zhao, H.T.</creator><creator>Sun, C.H.</creator><creator>Cui, J.</creator><general>Elsevier Ltd</general><general>[Amsterdam]: Elsevier Science</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20110715</creationdate><title>Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography–mass spectrometry: Determination of 88 pesticides in berries using SPE and GC–MS</title><author>Yang, X. ; Zhang, H. ; Liu, Y. ; Wang, J. ; Zhang, Y.C. ; Dong, A.J. ; Zhao, H.T. ; Sun, C.H. ; Cui, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-bc5e556a7b80a182a73b005146edc962345807c1bb7096a65ae452dadd81b8593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Berry fruits</topic><topic>Biological and medical sciences</topic><topic>Food industries</topic><topic>Fruit and vegetable industries</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>GC–MS</topic><topic>Multi-residue analysis</topic><topic>Pesticides</topic><topic>SPE</topic><topic>Validation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, X.</creatorcontrib><creatorcontrib>Zhang, H.</creatorcontrib><creatorcontrib>Liu, Y.</creatorcontrib><creatorcontrib>Wang, J.</creatorcontrib><creatorcontrib>Zhang, Y.C.</creatorcontrib><creatorcontrib>Dong, A.J.</creatorcontrib><creatorcontrib>Zhao, H.T.</creatorcontrib><creatorcontrib>Sun, C.H.</creatorcontrib><creatorcontrib>Cui, J.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, X.</au><au>Zhang, H.</au><au>Liu, Y.</au><au>Wang, J.</au><au>Zhang, Y.C.</au><au>Dong, A.J.</au><au>Zhao, H.T.</au><au>Sun, C.H.</au><au>Cui, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography–mass spectrometry: Determination of 88 pesticides in berries using SPE and GC–MS</atitle><jtitle>Food chemistry</jtitle><addtitle>Food Chem</addtitle><date>2011-07-15</date><risdate>2011</risdate><volume>127</volume><issue>2</issue><spage>855</spage><epage>865</epage><pages>855-865</pages><issn>0308-8146</issn><eissn>1873-7072</eissn><coden>FOCHDJ</coden><abstract>► The focus is simultaneous determination of 88 pesticides in berry with SPE-GC-MS. ► It is a rapid and reliable method that we have developed to analyze 88 pesticides. ► It is the first time to analyze 88 pesticide residues in raspberry and blueberry.
A method using solid phase extraction (SPE) cleanup followed by gas chromatography–mass spectrometry (GC–MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC–MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile–toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2⩾0.99. At the low, medium and high three fortification levels of 0.05–0.5mgkg−1, recoveries fell within 63–137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006–0.05mgkg−1) and quantification (0.02–0.15mgkg−1) were readily achieved with this method for all tested pesticides.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>23140746</pmid><doi>10.1016/j.foodchem.2011.01.024</doi><tpages>11</tpages></addata></record> |
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| subjects | Berry fruits Biological and medical sciences Food industries Fruit and vegetable industries Fundamental and applied biological sciences. Psychology GC–MS Multi-residue analysis Pesticides SPE Validation |
| title | Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography–mass spectrometry: Determination of 88 pesticides in berries using SPE and GC–MS |
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