Kinetic and Mechanistic Aspects of Atom Transfer Radical Addition (ATRA) Catalyzed by Copper Complexes with Tris(2-pyridylmethyl)amine

Kinetic and mechanistic studies of atom transfer radical addition (ATRA) catalyzed by copper complexes with tris(2-pyridylmethyl)amine (TPMA) ligand were reported. In solution, the halide anions were found to strongly coordinate to [CuI(TPMA)]+ cations, as confirmed by kinetic, cyclic voltammetry, a...

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Veröffentlicht in:	Inorganic chemistry 2012-11, Vol.51 (21), p.11917-11929
Hauptverfasser:	Eckenhoff, William T, Biernesser, Ashley B, Pintauer, Tomislav
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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