Directly Linked Corrole Oligomers via Facile Oxidative 3–3′ Coupling Reaction
Upon heating with p-chloranil in CHCl3, 5,10,15-tris(pentafluorophenyl)corrole (1H) underwent regioselective oxidative coupling reaction at the 3,3′-position to give dimer 2H and trimer 3H. Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. The crystal structures have been revealed fo...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2012-05, Vol.85 (5), p.558-562 |
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| container_title | Bulletin of the Chemical Society of Japan |
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| creator | Hirabayashi, Sho Omote, Masato Aratani, Naoki Osuka, Atsuhiro |
| description | Upon heating with p-chloranil in CHCl3, 5,10,15-tris(pentafluorophenyl)corrole (1H) underwent regioselective oxidative coupling reaction at the 3,3′-position to give dimer 2H and trimer 3H. Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. The crystal structures have been revealed for 2H, cobalt(III) complexed trimer 3Co·py6, and tetramer 4Co·py8. |
| doi_str_mv | 10.1246/bcsj.20110373 |
| format | Article |
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Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. 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Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. The crystal structures have been revealed for 2H, cobalt(III) complexed trimer 3Co·py6, and tetramer 4Co·py8.</description><subject>Crystal structure</subject><subject>Dimers</subject><subject>Heating</subject><subject>Joining</subject><subject>Oligomers</subject><subject>Oxidation</subject><subject>Trimers</subject><issn>0009-2673</issn><issn>1348-0634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkM1Kw0AQgBdRsFaP3gNevKTuf7LepFoVCqLoOWw3k7oxydbdpNib7-Cb-Eg-iSmtIOJhGGb45ocPoWOCR4RyeTYzoRxRTAhmCdtBA8J4GmPJ-C4aYIxVTGXC9tFBCGVfpoKrAbq_tB5MW62iqW1eII_GzntXQXRX2bmrwYdoaXU00caum282161dQsS-3j_6-Oz5blHZZh49gDatdc0h2it0FeBom4foaXL1OL6Jp3fXt-OLaWy4Sts44Rh4QrEAUlCpJAdFjaGmUEpxIkGSPAdMZqlJiMZEy5kGlVLBqRRECM2G6HSzd-HdawehzWobDFSVbsB1ISOEScGkTHGPnvxBS9f5pv8uI1wowSjuNQ1RvKGMdyF4KLKFt7X2q4zgbC04WwvOfgT3_PmWf4bamn6bMxbaVakXuvl14d_hb5EqgiQ</recordid><startdate>20120515</startdate><enddate>20120515</enddate><creator>Hirabayashi, Sho</creator><creator>Omote, Masato</creator><creator>Aratani, Naoki</creator><creator>Osuka, Atsuhiro</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120515</creationdate><title>Directly Linked Corrole Oligomers via Facile Oxidative 3–3′ Coupling Reaction</title><author>Hirabayashi, Sho ; Omote, Masato ; Aratani, Naoki ; Osuka, Atsuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c498t-740e47205e1f26964e92cc2cf999416e61dde01b8c71a01a6bae98254265155a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Crystal structure</topic><topic>Dimers</topic><topic>Heating</topic><topic>Joining</topic><topic>Oligomers</topic><topic>Oxidation</topic><topic>Trimers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hirabayashi, Sho</creatorcontrib><creatorcontrib>Omote, Masato</creatorcontrib><creatorcontrib>Aratani, Naoki</creatorcontrib><creatorcontrib>Osuka, Atsuhiro</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Bulletin of the Chemical Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hirabayashi, Sho</au><au>Omote, Masato</au><au>Aratani, Naoki</au><au>Osuka, Atsuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Directly Linked Corrole Oligomers via Facile Oxidative 3–3′ Coupling Reaction</atitle><jtitle>Bulletin of the Chemical Society of Japan</jtitle><addtitle>Bulletin of the Chemical Society of Japan</addtitle><date>2012-05-15</date><risdate>2012</risdate><volume>85</volume><issue>5</issue><spage>558</spage><epage>562</epage><pages>558-562</pages><issn>0009-2673</issn><eissn>1348-0634</eissn><abstract>Upon heating with p-chloranil in CHCl3, 5,10,15-tris(pentafluorophenyl)corrole (1H) underwent regioselective oxidative coupling reaction at the 3,3′-position to give dimer 2H and trimer 3H. Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. The crystal structures have been revealed for 2H, cobalt(III) complexed trimer 3Co·py6, and tetramer 4Co·py8.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/bcsj.20110373</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Bulletin of the Chemical Society of Japan, 2012-05, Vol.85 (5), p.558-562 |
| issn | 0009-2673 1348-0634 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1136536680 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Crystal structure Dimers Heating Joining Oligomers Oxidation Trimers |
| title | Directly Linked Corrole Oligomers via Facile Oxidative 3–3′ Coupling Reaction |
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