Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol-vinyl monomer copolymers

Inspired by the enzymatic ping-pong mechanism, we designed a novel "ping-pong polymerization", which employs allylation and hydroformylation in an iterative and alternating manner. Thus, alternating and regioregular vinyl alcohol-vinyl monomer copolymers possessing multiple hydroxy groups...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (85), p.10481-10483
Hauptverfasser:	Ito, Shingo, Noguchi, Masaki, Nozaki, Kyoko
Format:	Artikel
Sprache:	eng
Schlagworte:	Boronic Acids - chemistry Copolymers Monomers Polymerization Polymers - chemistry Polyvinyl Chloride - chemistry Polyvinyls - chemistry Stereoisomerism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Inspired by the enzymatic ping-pong mechanism, we designed a novel "ping-pong polymerization", which employs allylation and hydroformylation in an iterative and alternating manner. Thus, alternating and regioregular vinyl alcohol-vinyl monomer copolymers possessing multiple hydroxy groups in a periodical manner were successfully synthesized.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c2cc34980a