Preparation of aluminum-doped zinc oxide (AZO) nano particles by hydrothermal synthesis
Aluminum doped zinc oxide (AZO) nanometric particles were synthesized by hydrothermal method. Aluminum nitrate hydrate, aluminum sec-butoxide and zinc nitrate hydrate were used as the starting materials, and n-propanol and 2-butanol were used as solvents. Ratio of Al 2 O 3 in ZnO was kept at 10 wt%....
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| Veröffentlicht in: | Journal of sol-gel science and technology 2010-08, Vol.55 (2), p.171-176 |
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| creator | Burunkaya, Esin Kiraz, Nadir Kesmez, Ömer Erdem Çamurlu, H. Asiltürk, Meltem Arpaç, Ertuğrul |
| description | Aluminum doped zinc oxide (AZO) nanometric particles were synthesized by hydrothermal method. Aluminum nitrate hydrate, aluminum sec-butoxide and zinc nitrate hydrate were used as the starting materials, and n-propanol and 2-butanol were used as solvents. Ratio of Al
2
O
3
in ZnO was kept at 10 wt%. Reaction was conducted in a Teflon autoclave at 175–225 °C for 5 h. Ratios of alcohol, H
2
O and HCl to zinc nitrate hydrate were altered and 6 different sets of parameters were investigated. Obtained products were subjected to powder-XRD, particle size measurement, TEM examination and AAS analysis. Single phase AZO particles were obtained at alcohol to zinc nitrate ratio of 35, acid to zinc nitrate ratio of 0.2, at 225 °C. Particle size was determined as 3.2 ± 0.4 nm from TEM examinations and as 1–2 nm from dynamic light scattering. Synthesized particles have amphiphilic character, thus they can be dispersed in both polar and non-polar media. It was seen from the UV-diffuse reflectance spectra that the AZO powder had low reflectance in the UV region and high reflectance in the visible region. The obtained powder has the potential to be utilized in the form of thin films for optical and electronic purposes. |
| doi_str_mv | 10.1007/s10971-010-2229-2 |
| format | Article |
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2
O
3
in ZnO was kept at 10 wt%. Reaction was conducted in a Teflon autoclave at 175–225 °C for 5 h. Ratios of alcohol, H
2
O and HCl to zinc nitrate hydrate were altered and 6 different sets of parameters were investigated. Obtained products were subjected to powder-XRD, particle size measurement, TEM examination and AAS analysis. Single phase AZO particles were obtained at alcohol to zinc nitrate ratio of 35, acid to zinc nitrate ratio of 0.2, at 225 °C. Particle size was determined as 3.2 ± 0.4 nm from TEM examinations and as 1–2 nm from dynamic light scattering. Synthesized particles have amphiphilic character, thus they can be dispersed in both polar and non-polar media. It was seen from the UV-diffuse reflectance spectra that the AZO powder had low reflectance in the UV region and high reflectance in the visible region. The obtained powder has the potential to be utilized in the form of thin films for optical and electronic purposes.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-010-2229-2</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Alcohol ; Aluminum ; Aluminum oxide ; Autoclaving ; Azo ; Butanol ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Composites ; Exact sciences and technology ; General and physical chemistry ; Glass ; Hydrates ; Inorganic Chemistry ; Materials Science ; Nanostructure ; Nanotechnology ; Natural Materials ; Nitrates ; Optical and Electronic Materials ; Original Paper ; Particle size ; Photon correlation spectroscopy ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Polytetrafluoroethylene ; Reflectance ; Synthesis ; Thin films ; Zinc ; Zinc oxide ; Zinc oxides</subject><ispartof>Journal of sol-gel science and technology, 2010-08, Vol.55 (2), p.171-176</ispartof><rights>Springer Science+Business Media, LLC 2010</rights><rights>2015 INIST-CNRS</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2010). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c379t-199871cde0ec3a0da82fa359828bfbe97aae9c3f3534749a714298e4911148a03</citedby><cites>FETCH-LOGICAL-c379t-199871cde0ec3a0da82fa359828bfbe97aae9c3f3534749a714298e4911148a03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-010-2229-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-010-2229-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23089020$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Burunkaya, Esin</creatorcontrib><creatorcontrib>Kiraz, Nadir</creatorcontrib><creatorcontrib>Kesmez, Ömer</creatorcontrib><creatorcontrib>Erdem Çamurlu, H.</creatorcontrib><creatorcontrib>Asiltürk, Meltem</creatorcontrib><creatorcontrib>Arpaç, Ertuğrul</creatorcontrib><title>Preparation of aluminum-doped zinc oxide (AZO) nano particles by hydrothermal synthesis</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>Aluminum doped zinc oxide (AZO) nanometric particles were synthesized by hydrothermal method. Aluminum nitrate hydrate, aluminum sec-butoxide and zinc nitrate hydrate were used as the starting materials, and n-propanol and 2-butanol were used as solvents. Ratio of Al
2
O
3
in ZnO was kept at 10 wt%. Reaction was conducted in a Teflon autoclave at 175–225 °C for 5 h. Ratios of alcohol, H
2
O and HCl to zinc nitrate hydrate were altered and 6 different sets of parameters were investigated. Obtained products were subjected to powder-XRD, particle size measurement, TEM examination and AAS analysis. Single phase AZO particles were obtained at alcohol to zinc nitrate ratio of 35, acid to zinc nitrate ratio of 0.2, at 225 °C. Particle size was determined as 3.2 ± 0.4 nm from TEM examinations and as 1–2 nm from dynamic light scattering. Synthesized particles have amphiphilic character, thus they can be dispersed in both polar and non-polar media. It was seen from the UV-diffuse reflectance spectra that the AZO powder had low reflectance in the UV region and high reflectance in the visible region. The obtained powder has the potential to be utilized in the form of thin films for optical and electronic purposes.</description><subject>Alcohol</subject><subject>Aluminum</subject><subject>Aluminum oxide</subject><subject>Autoclaving</subject><subject>Azo</subject><subject>Butanol</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glass</subject><subject>Hydrates</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Nitrates</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Particle size</subject><subject>Photon correlation spectroscopy</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Polytetrafluoroethylene</subject><subject>Reflectance</subject><subject>Synthesis</subject><subject>Thin films</subject><subject>Zinc</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEFrFTEUhYMo-Kz-AHcBEeoiem-SaZJlKdUWCnWhCG7CfZmMTZlJnskM-Pz1zvMVBcFVLuQ7h8PH2EuEtwhg3jUEZ1AAgpBSOiEfsQ12Rglt9dljtgEnrQAD5il71to9AHQazYZ9-VjjjirNqWReBk7jMqW8TKIvu9jznykHXn6kPvLT86-3b3imXPgamFMYY-PbPb_b97XMd7FONPK2z-vZUnvOngw0tvji4T1hn99ffrq4Eje3H64vzm9EUMbNAp2zBkMfIQZF0JOVA6nOWWm3wzY6QxRdUIPqlDbakUEtnY3aIaK2BOqEnR57d7V8X2Kb_ZRaiONIOZaleUR1prRzGlf01T_ofVlqXtd5KTvXqU7-pvBIhVpaq3Hwu5omqnuP4A-q_VG1X1X7g2ov18zrh2ZqgcahUg6p_QlKBdaBPIyVR66tX_lbrH8X_L_8F5fdjPY</recordid><startdate>20100801</startdate><enddate>20100801</enddate><creator>Burunkaya, Esin</creator><creator>Kiraz, Nadir</creator><creator>Kesmez, Ömer</creator><creator>Erdem Çamurlu, H.</creator><creator>Asiltürk, Meltem</creator><creator>Arpaç, Ertuğrul</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7QF</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100801</creationdate><title>Preparation of aluminum-doped zinc oxide (AZO) nano particles by hydrothermal synthesis</title><author>Burunkaya, Esin ; Kiraz, Nadir ; Kesmez, Ömer ; Erdem Çamurlu, H. ; Asiltürk, Meltem ; Arpaç, Ertuğrul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c379t-199871cde0ec3a0da82fa359828bfbe97aae9c3f3534749a714298e4911148a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Alcohol</topic><topic>Aluminum</topic><topic>Aluminum oxide</topic><topic>Autoclaving</topic><topic>Azo</topic><topic>Butanol</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glass</topic><topic>Hydrates</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Nitrates</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Particle size</topic><topic>Photon correlation spectroscopy</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Polytetrafluoroethylene</topic><topic>Reflectance</topic><topic>Synthesis</topic><topic>Thin films</topic><topic>Zinc</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burunkaya, Esin</creatorcontrib><creatorcontrib>Kiraz, Nadir</creatorcontrib><creatorcontrib>Kesmez, Ömer</creatorcontrib><creatorcontrib>Erdem Çamurlu, H.</creatorcontrib><creatorcontrib>Asiltürk, Meltem</creatorcontrib><creatorcontrib>Arpaç, Ertuğrul</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burunkaya, Esin</au><au>Kiraz, Nadir</au><au>Kesmez, Ömer</au><au>Erdem Çamurlu, H.</au><au>Asiltürk, Meltem</au><au>Arpaç, Ertuğrul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of aluminum-doped zinc oxide (AZO) nano particles by hydrothermal synthesis</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2010-08-01</date><risdate>2010</risdate><volume>55</volume><issue>2</issue><spage>171</spage><epage>176</epage><pages>171-176</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>Aluminum doped zinc oxide (AZO) nanometric particles were synthesized by hydrothermal method. Aluminum nitrate hydrate, aluminum sec-butoxide and zinc nitrate hydrate were used as the starting materials, and n-propanol and 2-butanol were used as solvents. Ratio of Al
2
O
3
in ZnO was kept at 10 wt%. Reaction was conducted in a Teflon autoclave at 175–225 °C for 5 h. Ratios of alcohol, H
2
O and HCl to zinc nitrate hydrate were altered and 6 different sets of parameters were investigated. Obtained products were subjected to powder-XRD, particle size measurement, TEM examination and AAS analysis. Single phase AZO particles were obtained at alcohol to zinc nitrate ratio of 35, acid to zinc nitrate ratio of 0.2, at 225 °C. Particle size was determined as 3.2 ± 0.4 nm from TEM examinations and as 1–2 nm from dynamic light scattering. Synthesized particles have amphiphilic character, thus they can be dispersed in both polar and non-polar media. It was seen from the UV-diffuse reflectance spectra that the AZO powder had low reflectance in the UV region and high reflectance in the visible region. The obtained powder has the potential to be utilized in the form of thin films for optical and electronic purposes.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10971-010-2229-2</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of sol-gel science and technology, 2010-08, Vol.55 (2), p.171-176 |
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| subjects | Alcohol Aluminum Aluminum oxide Autoclaving Azo Butanol Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Exact sciences and technology General and physical chemistry Glass Hydrates Inorganic Chemistry Materials Science Nanostructure Nanotechnology Natural Materials Nitrates Optical and Electronic Materials Original Paper Particle size Photon correlation spectroscopy Physical and chemical studies. Granulometry. Electrokinetic phenomena Polytetrafluoroethylene Reflectance Synthesis Thin films Zinc Zinc oxide Zinc oxides |
| title | Preparation of aluminum-doped zinc oxide (AZO) nano particles by hydrothermal synthesis |
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