Nickel-Catalyzed Synthesis of Diarylamines via Oxidatively Induced C–N Bond Formation at Room Temperature

A nickel-catalyzed oxidative coupling of zinc amides with organomagnesium compounds selectively produces diarylamines under mild reaction conditions, with tolerance for chloride, bromide, hydroxyl, ester, and ketone groups. A diamine is bis-monoarylated. A bromoaniline undergoes N-arylation followed...

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Veröffentlicht in:	Organic letters 2012-11, Vol.14 (21), p.5570-5573
Hauptverfasser:	Ilies, Laurean, Matsubara, Tatsuaki, Nakamura, Eiichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Catalysis Diamines - chemical synthesis Diamines - chemistry Hydrocarbons, Halogenated - chemistry Molecular Structure Nickel - chemistry Oxidation-Reduction Temperature
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