Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

A series of organically templated vanadium selenites have been prepared under mild hydrothermal conditions. Single crystals were grown from mixtures of VOSO4, SeO2, and either 1,4-dimethylpiperazine, 2,5-dimethylpiperazine, or 2-methylpiperazine in H2O. Each compound contains one-dimensional [VO(SeO...

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Veröffentlicht in:Inorganic chemistry 2012-10, Vol.51 (20), p.11040-11048
Hauptverfasser: Olshansky, Jacob H, Thao Tran, Thanh, Hernandez, Kristen J, Zeller, Matthias, Halasyamani, P. Shiv, Schrier, Joshua, Norquist, Alexander J
Format: Artikel
Sprache:eng
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