Highly Flexible Molecule “Chameleon”: Reversible Thermochromism and Phase Transitions in Solid Copper(II) Diiminate Cu[CF3C(NH)CFC(NH)CF3]2

Three thermochromic phases (α, green; β, red; γ, yellow) and six polymorphic modifications (α1, monoclinic, P21/n, Z = 2; β1, monoclinic, P21/c, Z = 4; β2, triclinic, P1̅, Z = 4; β3, monoclinic, P21/n, Z = 4; γ1 and γ2, tetragonal, P42/n, Z = 4) have been found and structurally characterized for cop...

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Veröffentlicht in:Inorganic chemistry 2012-10, Vol.51 (20), p.10590-10602
Hauptverfasser: Khrustalev, Victor N, Kostenko, Svetlana O, Buzin, Mikhail I, Korlyukov, Alexander A, Zubavichus, Yan V, Kurykin, Michael A, Antipin, Mikhail Yu
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Sprache:eng
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