Telomerisation of Buta-1,3-diene and Methanol: Superiority of Chromanyl-Type Phosphines in the Dow Process for the Industrial Production of 1-MOD

Butadiene and methanol were telomerised in the presence of palladium catalysts with ligands containing 8‐diphenylphosphinochromane‐like substituents at phosphorus. MonoXantphos and monoSPANphos afforded the most active, stable and selective catalysts known to date under commercially relevant product...

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Veröffentlicht in:	Chemistry : a European journal 2011-08, Vol.17 (32), p.8922-8928
Hauptverfasser:	Tschan, Mathieu J.-L., Launay, Hélène, Hagen, Henk, Benet-Buchholz, Jordi, van Leeuwen, Piet W. N. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbenes Chemistry ligand design palladium phosphane ligands telomerisation
Online-Zugang:	Volltext
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