Examples of Regioselective Anion Recognition among a Family of Two‑, Three‑, and Four-“Armed” Bis‑, Tris‑, and Tetrakis(thioureido) [n]Polynorbornane hosts

A family of conformationally preorganized, [n]polynorbornane-based anion hosts 1a,b–6a,b have been synthesized. The series includes receptors with 4, 8, and 12 H-bond donors. Using 1H NMR titration techniques, evaluation of the new hosts against a series of alkyl and aryl dicarboxylates as well as a...

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Veröffentlicht in:	Journal of organic chemistry 2012-10, Vol.77 (19), p.8507-8517
Hauptverfasser:	Lowe, Adam J, Long, Benjamin M, Pfeffer, Frederick M
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Anions - chemistry Chemistry Exact sciences and technology Heterocyclic compounds Magnetic Resonance Spectroscopy Molecular Conformation Molecular Structure Norbornanes - chemistry Organic chemistry Organophosphates - chemistry Preparations and properties Stereoisomerism Thiourea - chemistry
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