Effect of Oil/Water Ratios on the Phase Behavior and the Solubilization Ability of Microemulsion Systems Containing Sodium Dodecyl Sulfate

An α – ε – β fish-like phase diagram of three phase microemulsions was proposed and used to investigate the phase behavior of the microemulsion systems sodium dodecyl sulfate (SDS)/alcohol/oil/water at various oil/water ratios. Related physicochemical properties of the microemulsion systems were cal...

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Veröffentlicht in:Journal of solution chemistry 2011-11, Vol.40 (11), p.1889-1898
Hauptverfasser: Chai, Jin-Ling, Wu, Yu-Tong, Li, Xun-Qiang, Yang, Bao, Lu, Jian-Jun
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container_end_page 1898
container_issue 11
container_start_page 1889
container_title Journal of solution chemistry
container_volume 40
creator Chai, Jin-Ling
Wu, Yu-Tong
Li, Xun-Qiang
Yang, Bao
Lu, Jian-Jun
description An α – ε – β fish-like phase diagram of three phase microemulsions was proposed and used to investigate the phase behavior of the microemulsion systems sodium dodecyl sulfate (SDS)/alcohol/oil/water at various oil/water ratios. Related physicochemical properties of the microemulsion systems were calculated. As the oil/water mass ratio increases, the solubility ( ε B ) of the alcohol increases, while both the mass fraction of alcohol in the interfacial layer ( A S ) and the solubilization ability ( SP ∗ ) decrease. The effect of oils on the properties of the microemulsion systems was investigated.
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subjects Alcohols
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Geochemistry
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Mathematical analysis
Microemulsions
Oceanography
Phase diagrams
Physical Chemistry
Sodium
Solubility
Solubilization
Sulfates
title Effect of Oil/Water Ratios on the Phase Behavior and the Solubilization Ability of Microemulsion Systems Containing Sodium Dodecyl Sulfate
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