FeCl sub(3)/Montmorillonite K10 as an efficient catalyst for solvent-free aza-Michael reaction between amine and alpha , beta -unsaturated compounds

FeCl sub(3)/Montmorillonite K10 as an efficient catalyst for solvent-free aza-Michael reaction between amine and alpha , beta -unsaturated compounds

A highly efficient, inexpensive and greener protocol for aza-Michael addition reaction of different aromatic and aliphatic/cyclic amines to alpha , beta -unsaturated compounds using a FeCl sub(3)/MontK10 catalyst under solvent-free conditions has been developed. The Michael addition products are obt...

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Veröffentlicht in:RSC advances 2012-07, Vol.2 (18), p.7061-7065
Hauptverfasser: Choudhary, V R, Dumbre, D K, Patil, S K
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Sprache:eng
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Aliphatic compounds
Amines
Aromatic compounds
Catalysts
Moisture
Montmorillonite
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creator Choudhary, V R
Dumbre, D K
Patil, S K
description A highly efficient, inexpensive and greener protocol for aza-Michael addition reaction of different aromatic and aliphatic/cyclic amines to alpha , beta -unsaturated compounds using a FeCl sub(3)/MontK10 catalyst under solvent-free conditions has been developed. The Michael addition products are obtained in good to excellent yields. The catalyst was insensitive to moisture and it also showed excellent reusability in the reaction. Its high activity is attributed mostly to redox properties of FeCl sub(3.)
doi_str_mv 10.1039/c2ra01323a
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source Royal Society Of Chemistry Journals 2008-
subjects Aliphatic compounds
Amines
Aromatic compounds
Catalysts
Moisture
Montmorillonite
title FeCl sub(3)/Montmorillonite K10 as an efficient catalyst for solvent-free aza-Michael reaction between amine and alpha , beta -unsaturated compounds
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