An AFM/EFM Study of the Grain Boundary in ZnO-Based Varistor Materials

Zinc oxide (ZnO)‐based varistors are metal oxide varistors whose nonlinear properties are characterized by electrical resistance that decreases as the applied field increases. The multiphasic nature of varistors leads to the formation of Schottky barriers, which are responsible for the materials...

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Veröffentlicht in:Journal of the American Ceramic Society 2008-11, Vol.91 (11), p.3593-3598
Hauptverfasser: Gheno, Simoni M., Kiminami, Ruth H. G. A., Morelli, Márcio M., Bellini, Jusmar V., Paulin Filho, Pedro I.
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container_issue 11
container_start_page 3593
container_title Journal of the American Ceramic Society
container_volume 91
creator Gheno, Simoni M.
Kiminami, Ruth H. G. A.
Morelli, Márcio M.
Bellini, Jusmar V.
Paulin Filho, Pedro I.
description Zinc oxide (ZnO)‐based varistors are metal oxide varistors whose nonlinear properties are characterized by electrical resistance that decreases as the applied field increases. The multiphasic nature of varistors leads to the formation of Schottky barriers, which are responsible for the materials' nonlinear behavior. The objective of this work was to image the potential barriers in ZnO doped with 0.5 mol% Cu and x wt% G (G is a frit and x=0, 1, and 5 wt%). The frit served to form a glassy insulating layer around the grain boundaries. Samples were sintered at 1050°C and the microstructures were analyzed using a Nanoscope IIIa atomic force microscope. The results of the electric force microscopy experiments map the electric field distribution on the surface of CuO–ZnO‐based ceramics.
doi_str_mv 10.1111/j.1551-2916.2008.02704.x
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subjects Applied sciences
BOUNDARIES
Building materials. Ceramics. Glasses
Ceramic industries
Ceramic sintering
Ceramics
Chemical industry and chemicals
Conductors, resistors (including thermistors, varistors, and photoresistors)
COPPER OXIDE
Crystal structure
Electronic devices
Electronic equipment and fabrication. Passive components, printed wiring boards, connectics
ELECTRONIC PRODUCTS
Electronics
Electrotechnical and electronic ceramics
Exact sciences and technology
Frit
GRAIN BOUNDARIES
Materials science
Microscopy
MICROSTRUCTURES
Nanostructure
Nonlinearity
Technical ceramics
Varistors
ZINC OXIDE
Zinc oxides
title An AFM/EFM Study of the Grain Boundary in ZnO-Based Varistor Materials
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