Synthesis Mechanism of an Iron-Chromium Ceramic Pigment

The synthesis of a black Fe2O3–Cr2O3 pigment has been studied to better understand the synthesis mechanism. A mechanism is proposed according to which, under the tested operating conditions, one of the starting constituents (Cr2O3) is transferred, largely in a gas phase (after subliming), to the par...

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Veröffentlicht in:Journal of the American Ceramic Society 2000-01, Vol.83 (1), p.29-32
Hauptverfasser: Escardino, Agustín, Mestre, Sergio, Barba, Antonio, Beltrán, Vicente, Blasco, Antonio
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container_issue 1
container_start_page 29
container_title Journal of the American Ceramic Society
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creator Escardino, Agustín
Mestre, Sergio
Barba, Antonio
Beltrán, Vicente
Blasco, Antonio
description The synthesis of a black Fe2O3–Cr2O3 pigment has been studied to better understand the synthesis mechanism. A mechanism is proposed according to which, under the tested operating conditions, one of the starting constituents (Cr2O3) is transferred, largely in a gas phase (after subliming), to the particle surface of the other constituent (Fe2O3), at which it is deposited or chemisorbed, forming a layer from which it diffuses inward into the Fe2O3 particles. The process stops when the composition of the resulting solid solution has become uniform.
doi_str_mv 10.1111/j.1151-2916.2000.tb01143.x
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subjects Ceramics
chromium oxide
Constituents
Deposition
Diffusion
pigment
Pigments
Plugs
Solid solutions
Synthesis
title Synthesis Mechanism of an Iron-Chromium Ceramic Pigment
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