Electrodeposition and characterization of CdSe semiconductor thin films
The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on...
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Veröffentlicht in: | Journal of materials science. Materials in electronics 2007-06, Vol.18 (6), p.575-585 |
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creator | RASHWAN, S. M ABD EL-WAHAB, S. M MOHAMED, M. M |
description | The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on the electrodeposited layers was obtained by X-ray diffraction. The experimental results clearly show that the deposition of cadmium selenide alloy on glassy carbon and gold electrodes is a diffusion-controlled process. The nucleation is progressive, and the number of nucleation sites decreases with increasing bath temperature. The deposition of CdSe alloy results in well-defined crystals with hexagonal shape. The films were characterized by optical absorption and electrical resistivity measurements. Films showed a direct band gap of 3.56 eV. |
doi_str_mv | 10.1007/s10854-007-9141-8 |
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M ; ABD EL-WAHAB, S. M ; MOHAMED, M. M</creator><creatorcontrib>RASHWAN, S. M ; ABD EL-WAHAB, S. M ; MOHAMED, M. M</creatorcontrib><description>The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on the electrodeposited layers was obtained by X-ray diffraction. The experimental results clearly show that the deposition of cadmium selenide alloy on glassy carbon and gold electrodes is a diffusion-controlled process. The nucleation is progressive, and the number of nucleation sites decreases with increasing bath temperature. The deposition of CdSe alloy results in well-defined crystals with hexagonal shape. The films were characterized by optical absorption and electrical resistivity measurements. Films showed a direct band gap of 3.56 eV.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-007-9141-8</identifier><language>eng</language><publisher>Norwell, MA: Springer</publisher><subject>Applied sciences ; Cadmium selenide ; Cadmium selenides ; Chemistry ; Deposition ; Electrodeposition ; Electrodes ; Electronics ; Exact sciences and technology ; Glassy carbon ; Gold ; Intermetallics ; Materials ; Metallurgy ; Microelectronic fabrication (materials and surfaces technology) ; Nucleation ; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices ; Semiconductors ; Thin films</subject><ispartof>Journal of materials science. 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M</creatorcontrib><title>Electrodeposition and characterization of CdSe semiconductor thin films</title><title>Journal of materials science. Materials in electronics</title><description>The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on the electrodeposited layers was obtained by X-ray diffraction. The experimental results clearly show that the deposition of cadmium selenide alloy on glassy carbon and gold electrodes is a diffusion-controlled process. The nucleation is progressive, and the number of nucleation sites decreases with increasing bath temperature. The deposition of CdSe alloy results in well-defined crystals with hexagonal shape. The films were characterized by optical absorption and electrical resistivity measurements. Films showed a direct band gap of 3.56 eV.</description><subject>Applied sciences</subject><subject>Cadmium selenide</subject><subject>Cadmium selenides</subject><subject>Chemistry</subject><subject>Deposition</subject><subject>Electrodeposition</subject><subject>Electrodes</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>Glassy carbon</subject><subject>Gold</subject><subject>Intermetallics</subject><subject>Materials</subject><subject>Metallurgy</subject><subject>Microelectronic fabrication (materials and surfaces technology)</subject><subject>Nucleation</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>RASHWAN, S. M</au><au>ABD EL-WAHAB, S. M</au><au>MOHAMED, M. M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodeposition and characterization of CdSe semiconductor thin films</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><date>2007-06-01</date><risdate>2007</risdate><volume>18</volume><issue>6</issue><spage>575</spage><epage>585</epage><pages>575-585</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on the electrodeposited layers was obtained by X-ray diffraction. The experimental results clearly show that the deposition of cadmium selenide alloy on glassy carbon and gold electrodes is a diffusion-controlled process. The nucleation is progressive, and the number of nucleation sites decreases with increasing bath temperature. The deposition of CdSe alloy results in well-defined crystals with hexagonal shape. The films were characterized by optical absorption and electrical resistivity measurements. Films showed a direct band gap of 3.56 eV.</abstract><cop>Norwell, MA</cop><pub>Springer</pub><doi>10.1007/s10854-007-9141-8</doi><tpages>11</tpages></addata></record> |
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subjects | Applied sciences Cadmium selenide Cadmium selenides Chemistry Deposition Electrodeposition Electrodes Electronics Exact sciences and technology Glassy carbon Gold Intermetallics Materials Metallurgy Microelectronic fabrication (materials and surfaces technology) Nucleation Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Semiconductors Thin films |
title | Electrodeposition and characterization of CdSe semiconductor thin films |
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