Electrodeposition and characterization of CdSe semiconductor thin films

The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2007-06, Vol.18 (6), p.575-585
Hauptverfasser: RASHWAN, S. M, ABD EL-WAHAB, S. M, MOHAMED, M. M
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container_title Journal of materials science. Materials in electronics
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creator RASHWAN, S. M
ABD EL-WAHAB, S. M
MOHAMED, M. M
description The electrodeposition of cadmium selenide alloy on glassy carbon and gold electrodes has been studied by electrochemical techniques. Potentiostatic I-t transients were recorded to obtain the nucleation mechanism, while cyclic voltammetry was used to characterize the system. Structural information on the electrodeposited layers was obtained by X-ray diffraction. The experimental results clearly show that the deposition of cadmium selenide alloy on glassy carbon and gold electrodes is a diffusion-controlled process. The nucleation is progressive, and the number of nucleation sites decreases with increasing bath temperature. The deposition of CdSe alloy results in well-defined crystals with hexagonal shape. The films were characterized by optical absorption and electrical resistivity measurements. Films showed a direct band gap of 3.56 eV.
doi_str_mv 10.1007/s10854-007-9141-8
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subjects Applied sciences
Cadmium selenide
Cadmium selenides
Chemistry
Deposition
Electrodeposition
Electrodes
Electronics
Exact sciences and technology
Glassy carbon
Gold
Intermetallics
Materials
Metallurgy
Microelectronic fabrication (materials and surfaces technology)
Nucleation
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Semiconductors
Thin films
title Electrodeposition and characterization of CdSe semiconductor thin films
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