Reversible Insertion of Platinum into Coinage Group Metal-Halogen Bonds

M&Ms: The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal‐only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a con...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-10, Vol.51 (40), p.10030-10033
Hauptverfasser:	Bauer, Jürgen, Braunschweig, Holger, Damme, Alexander, Radacki, Krzysztof
Format:	Artikel
Sprache:	eng
Schlagworte:	density functional calculations heterobimetallic complexes insertion Lewis pairs transition metals
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description	M&Ms: The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal‐only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a convenient route to mixed d10–d10 complexes.
doi_str_mv	10.1002/anie.201205438
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subjects	density functional calculations heterobimetallic complexes insertion Lewis pairs transition metals
title	Reversible Insertion of Platinum into Coinage Group Metal-Halogen Bonds
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