Reversible Insertion of Platinum into Coinage Group Metal-Halogen Bonds

Reversible Insertion of Platinum into Coinage Group Metal-Halogen Bonds

M&Ms: The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal‐only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a con...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (40), p.10030-10033
Hauptverfasser: Bauer, Jürgen, Braunschweig, Holger, Damme, Alexander, Radacki, Krzysztof
Format: Artikel
Sprache:eng
Schlagworte:
density functional calculations
heterobimetallic complexes
insertion
Lewis pairs
transition metals
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Zusammenfassung:M&Ms: The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal‐only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a convenient route to mixed d10–d10 complexes.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201205438