Ring splitting of azetidin-2-ones via radical anions

The radical anions of azetidin-2-ones, generated by UV-irradiation in the presence of triethylamine, undergo ring-splitting via N-C4 or C3-C4 bond breaking, leading to open-chain amides. This reactivity diverges from that found for the neutral excited states, which is characterised by α-cleavage. Th...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Organic & biomolecular chemistry 2012-10, Vol.10 (39), p.7928-7932
Hauptverfasser:	Pérez-Ruiz, Raúl, Sáez, Jose A, Domingo, Luis R, Jiménez, M Consuelo, Miranda, Miguel A
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Azetidines - chemical synthesis Azetidines - chemistry Free Radicals - chemistry Molecular Structure Quantum Theory Ultraviolet Rays
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!