Biodiesel Production from Sewage Sludge: New Paradigm for Mining Energy from Municipal Hazardous Material
This work demonstrates that the production of biodiesel using the lipids extracted from sewage sludge (SS) could be economically feasible because of the remarkably high yield of oil and low cost of this feedstock, as compared to conventional biodiesel feedstocks. The yield of oil from SS, 980 000 L...
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Veröffentlicht in: | Environmental science & technology 2012-09, Vol.46 (18), p.10222-10228 |
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description | This work demonstrates that the production of biodiesel using the lipids extracted from sewage sludge (SS) could be economically feasible because of the remarkably high yield of oil and low cost of this feedstock, as compared to conventional biodiesel feedstocks. The yield of oil from SS, 980 000 L ha–1 year–1, is superior to those from microalgal and soybean oils, 446 and 2200 L ha–1 year–1, respectively. According to the case study of South Korea, the price of the lipids extracted from SS was approximately $0.03 L–1 (USD), which is lower than those of all current biodiesel feedstocks. This work also highlights the insight of a novel methodology for transforming lipids containing high amounts of free fatty acids (FFAs) to biodiesel using a thermochemical process under ambient pressure in a continuous flow system. This allowed the combination of esterification of FFAs and transesterification of triglycerides into a single noncatalytic process, which led to a 98.5% ± 0.5% conversion efficiency to FAME (fatty acid methyl ester) within 1 min in a temperature range of 350–500 °C. The new process for converting the lipids extracted from SS shows high potential to achieve a major breakthrough in minimizing the cost of biodiesel production owing to its simplicity and technical advantages, as well as environmental benefits. |
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The yield of oil from SS, 980 000 L ha–1 year–1, is superior to those from microalgal and soybean oils, 446 and 2200 L ha–1 year–1, respectively. According to the case study of South Korea, the price of the lipids extracted from SS was approximately $0.03 L–1 (USD), which is lower than those of all current biodiesel feedstocks. This work also highlights the insight of a novel methodology for transforming lipids containing high amounts of free fatty acids (FFAs) to biodiesel using a thermochemical process under ambient pressure in a continuous flow system. This allowed the combination of esterification of FFAs and transesterification of triglycerides into a single noncatalytic process, which led to a 98.5% ± 0.5% conversion efficiency to FAME (fatty acid methyl ester) within 1 min in a temperature range of 350–500 °C. The new process for converting the lipids extracted from SS shows high potential to achieve a major breakthrough in minimizing the cost of biodiesel production owing to its simplicity and technical advantages, as well as environmental benefits.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es3019435</identifier><identifier>PMID: 22906253</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Alternative fuels. Production and utilization ; Applied sciences ; Biodiesel fuels ; Biofuels - analysis ; Biofuels - economics ; Energy ; Environmental science ; Esterification ; Exact sciences and technology ; Fatty acids ; Fatty Acids, Nonesterified - chemistry ; Fuels ; Hazardous materials ; Lipids ; Lipids - chemistry ; Lipids - isolation & purification ; Miscellaneous ; Other industrial wastes. Sewage sludge ; Pollution ; Raw materials ; Republic of Korea ; Sewage - chemistry ; Sludge ; Triglycerides - chemistry ; Wastes</subject><ispartof>Environmental science & technology, 2012-09, Vol.46 (18), p.10222-10228</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>2014 INIST-CNRS</rights><rights>Copyright American Chemical Society Sep 18, 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a373t-a33f97a40824bb493e133366e676ca49eed5af21a03a7b0068b7a98f96d6acb23</citedby><cites>FETCH-LOGICAL-a373t-a33f97a40824bb493e133366e676ca49eed5af21a03a7b0068b7a98f96d6acb23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es3019435$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es3019435$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26380090$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22906253$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kwon, Eilhann E</creatorcontrib><creatorcontrib>Kim, Sungpyo</creatorcontrib><creatorcontrib>Jeon, Young Jae</creatorcontrib><creatorcontrib>Yi, Haakrho</creatorcontrib><title>Biodiesel Production from Sewage Sludge: New Paradigm for Mining Energy from Municipal Hazardous Material</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>This work demonstrates that the production of biodiesel using the lipids extracted from sewage sludge (SS) could be economically feasible because of the remarkably high yield of oil and low cost of this feedstock, as compared to conventional biodiesel feedstocks. The yield of oil from SS, 980 000 L ha–1 year–1, is superior to those from microalgal and soybean oils, 446 and 2200 L ha–1 year–1, respectively. According to the case study of South Korea, the price of the lipids extracted from SS was approximately $0.03 L–1 (USD), which is lower than those of all current biodiesel feedstocks. This work also highlights the insight of a novel methodology for transforming lipids containing high amounts of free fatty acids (FFAs) to biodiesel using a thermochemical process under ambient pressure in a continuous flow system. This allowed the combination of esterification of FFAs and transesterification of triglycerides into a single noncatalytic process, which led to a 98.5% ± 0.5% conversion efficiency to FAME (fatty acid methyl ester) within 1 min in a temperature range of 350–500 °C. The new process for converting the lipids extracted from SS shows high potential to achieve a major breakthrough in minimizing the cost of biodiesel production owing to its simplicity and technical advantages, as well as environmental benefits.</description><subject>Alternative fuels. Production and utilization</subject><subject>Applied sciences</subject><subject>Biodiesel fuels</subject><subject>Biofuels - analysis</subject><subject>Biofuels - economics</subject><subject>Energy</subject><subject>Environmental science</subject><subject>Esterification</subject><subject>Exact sciences and technology</subject><subject>Fatty acids</subject><subject>Fatty Acids, Nonesterified - chemistry</subject><subject>Fuels</subject><subject>Hazardous materials</subject><subject>Lipids</subject><subject>Lipids - chemistry</subject><subject>Lipids - isolation & purification</subject><subject>Miscellaneous</subject><subject>Other industrial wastes. Sewage sludge</subject><subject>Pollution</subject><subject>Raw materials</subject><subject>Republic of Korea</subject><subject>Sewage - chemistry</subject><subject>Sludge</subject><subject>Triglycerides - chemistry</subject><subject>Wastes</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpd0MFO3DAQBmCralUWyqEvUFmqKsFhYWwnjt1bi6AgsRQJKvUWTZxJZJTEi70RgqcndLeAuIwvn2d-_Yx9FnAgQIpDSgqEzVT-js1ELmGem1y8ZzMAoeZW6b9bbDulGwCQCsxHtiWlBS1zNWP-pw-1p0Qdv4yhHt3Kh4E3MfT8iu6wJX7VjXVL3_kF3fFLjFj7tudNiHzhBz-0_Hig2N6vvyzGwTu_xI6f4gPGOoyJL3BF0WP3iX1osEu0u3l32J-T4-uj0_n5719nRz_O56gKtZqmamyBGRiZVVVmFQmllNakC-0ws0R1jo0UCAqLCkCbqkBrGqtrja6SaoftrfcuY7gdKa3K3idHXYcDTXlKAZkQmTTSTvTrG3oTxjhM6f4pKQwYM6n9tXIxpBSpKZfR9xjvJ1Q-9V8-9z_ZL5uNY9VT_Sz_Fz6BbxuAyWHXRBycTy9OKwNg4cWhS69TvT34CLo_l24</recordid><startdate>20120918</startdate><enddate>20120918</enddate><creator>Kwon, Eilhann E</creator><creator>Kim, Sungpyo</creator><creator>Jeon, Young Jae</creator><creator>Yi, Haakrho</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7T7</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope></search><sort><creationdate>20120918</creationdate><title>Biodiesel Production from Sewage Sludge: New Paradigm for Mining Energy from Municipal Hazardous Material</title><author>Kwon, Eilhann E ; Kim, Sungpyo ; Jeon, Young Jae ; Yi, Haakrho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a373t-a33f97a40824bb493e133366e676ca49eed5af21a03a7b0068b7a98f96d6acb23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Alternative fuels. Production and utilization</topic><topic>Applied sciences</topic><topic>Biodiesel fuels</topic><topic>Biofuels - analysis</topic><topic>Biofuels - economics</topic><topic>Energy</topic><topic>Environmental science</topic><topic>Esterification</topic><topic>Exact sciences and technology</topic><topic>Fatty acids</topic><topic>Fatty Acids, Nonesterified - chemistry</topic><topic>Fuels</topic><topic>Hazardous materials</topic><topic>Lipids</topic><topic>Lipids - chemistry</topic><topic>Lipids - isolation & purification</topic><topic>Miscellaneous</topic><topic>Other industrial wastes. Sewage sludge</topic><topic>Pollution</topic><topic>Raw materials</topic><topic>Republic of Korea</topic><topic>Sewage - chemistry</topic><topic>Sludge</topic><topic>Triglycerides - chemistry</topic><topic>Wastes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kwon, Eilhann E</creatorcontrib><creatorcontrib>Kim, Sungpyo</creatorcontrib><creatorcontrib>Jeon, Young Jae</creatorcontrib><creatorcontrib>Yi, Haakrho</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kwon, Eilhann E</au><au>Kim, Sungpyo</au><au>Jeon, Young Jae</au><au>Yi, Haakrho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biodiesel Production from Sewage Sludge: New Paradigm for Mining Energy from Municipal Hazardous Material</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>2012-09-18</date><risdate>2012</risdate><volume>46</volume><issue>18</issue><spage>10222</spage><epage>10228</epage><pages>10222-10228</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>This work demonstrates that the production of biodiesel using the lipids extracted from sewage sludge (SS) could be economically feasible because of the remarkably high yield of oil and low cost of this feedstock, as compared to conventional biodiesel feedstocks. The yield of oil from SS, 980 000 L ha–1 year–1, is superior to those from microalgal and soybean oils, 446 and 2200 L ha–1 year–1, respectively. According to the case study of South Korea, the price of the lipids extracted from SS was approximately $0.03 L–1 (USD), which is lower than those of all current biodiesel feedstocks. This work also highlights the insight of a novel methodology for transforming lipids containing high amounts of free fatty acids (FFAs) to biodiesel using a thermochemical process under ambient pressure in a continuous flow system. This allowed the combination of esterification of FFAs and transesterification of triglycerides into a single noncatalytic process, which led to a 98.5% ± 0.5% conversion efficiency to FAME (fatty acid methyl ester) within 1 min in a temperature range of 350–500 °C. The new process for converting the lipids extracted from SS shows high potential to achieve a major breakthrough in minimizing the cost of biodiesel production owing to its simplicity and technical advantages, as well as environmental benefits.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>22906253</pmid><doi>10.1021/es3019435</doi><tpages>7</tpages></addata></record> |
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subjects | Alternative fuels. Production and utilization Applied sciences Biodiesel fuels Biofuels - analysis Biofuels - economics Energy Environmental science Esterification Exact sciences and technology Fatty acids Fatty Acids, Nonesterified - chemistry Fuels Hazardous materials Lipids Lipids - chemistry Lipids - isolation & purification Miscellaneous Other industrial wastes. Sewage sludge Pollution Raw materials Republic of Korea Sewage - chemistry Sludge Triglycerides - chemistry Wastes |
title | Biodiesel Production from Sewage Sludge: New Paradigm for Mining Energy from Municipal Hazardous Material |
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