A sustainable route from the renewable myrcene to methyl ethers viadirect hydroalkoxylation

A direct route to odoriferous methyl ethers from the monoterpene myrcene is presented. Investigating the activity of different catalytically active Lewis acids, the non-toxic and low-cost AlCl sub(3) appeared to be very suitable. Thus, the common route to ethers viathe corresponding alcohols was red...

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Veröffentlicht in:Catalysis science & technology 2011-12, Vol.2 (1), p.88-92
Hauptverfasser: Behr, Arno, Johnen, Leif, Neubert, Peter
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description A direct route to odoriferous methyl ethers from the monoterpene myrcene is presented. Investigating the activity of different catalytically active Lewis acids, the non-toxic and low-cost AlCl sub(3) appeared to be very suitable. Thus, the common route to ethers viathe corresponding alcohols was reduced from four steps to one.
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title A sustainable route from the renewable myrcene to methyl ethers viadirect hydroalkoxylation
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