Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework
► One Ag(I) complex built from azelaic acid and 1,3-bis(4-pyridyl)propane was ultrasonically synthesized and characterized. ► Discrete (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters were accommodated in the channels. ► The complex exhibits strong photoluminescence maximized at 50...
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| Veröffentlicht in: | Journal of molecular structure 2012-08, Vol.1021, p.84-88 |
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| creator | Luo, Geng-Geng Zhu, Rui-Min He, Wei-Jun Li, Ming-Zhi Zhao, Qing-Hua Li, Dong-Xu Dai, Jing-Cao |
| description | ► One Ag(I) complex built from azelaic acid and 1,3-bis(4-pyridyl)propane was ultrasonically synthesized and characterized. ► Discrete (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters were accommodated in the channels. ► The complex exhibits strong photoluminescence maximized at 500nm upon 350nm excitation. ► CIE chromaticity ordinate of the emission is close to that of edge of green component.
Flexible azelaic acid (H2aze) and 1,3-bis(4-pyridyl)propane) (bpp) react ultrasonically with silver(I) oxide, generating a new metal–organic framework [Ag2(bpp)2(aze)·7H2O·CH3OH]n (1) that forms a 3D supramolecular structure through H-bonding interactions between solvent molecules and carboxylate O atoms with void spaces. Two kinds of solvent clusters, discrete cyclic (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters occupy the channels in the structure. Furthermore, 1 exhibits strong photoluminescence maximized at 500nm upon 350nm excitation at room temperature, of which CIE chromaticity ordinate (x=0.28, y=0.44) is close to that of edge of green component. |
| doi_str_mv | 10.1016/j.molstruc.2012.04.050 |
| format | Article |
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Flexible azelaic acid (H2aze) and 1,3-bis(4-pyridyl)propane) (bpp) react ultrasonically with silver(I) oxide, generating a new metal–organic framework [Ag2(bpp)2(aze)·7H2O·CH3OH]n (1) that forms a 3D supramolecular structure through H-bonding interactions between solvent molecules and carboxylate O atoms with void spaces. Two kinds of solvent clusters, discrete cyclic (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters occupy the channels in the structure. Furthermore, 1 exhibits strong photoluminescence maximized at 500nm upon 350nm excitation at room temperature, of which CIE chromaticity ordinate (x=0.28, y=0.44) is close to that of edge of green component.</description><identifier>ISSN: 0022-2860</identifier><identifier>EISSN: 1872-8014</identifier><identifier>DOI: 10.1016/j.molstruc.2012.04.050</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Atomic structure ; Azelate ; CIE chromaticity diagram ; hydrogen bonding ; Methanol–water binary cluster ; Photoluminescence ; propane ; silver ; temperature ; Water trimer</subject><ispartof>Journal of molecular structure, 2012-08, Vol.1021, p.84-88</ispartof><rights>2012 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c284t-ced9d31a5832d86ce80234c014b2b0b840893c58d9a46cd4bcf52eda3a26756b3</citedby><cites>FETCH-LOGICAL-c284t-ced9d31a5832d86ce80234c014b2b0b840893c58d9a46cd4bcf52eda3a26756b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022286012003742$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Luo, Geng-Geng</creatorcontrib><creatorcontrib>Zhu, Rui-Min</creatorcontrib><creatorcontrib>He, Wei-Jun</creatorcontrib><creatorcontrib>Li, Ming-Zhi</creatorcontrib><creatorcontrib>Zhao, Qing-Hua</creatorcontrib><creatorcontrib>Li, Dong-Xu</creatorcontrib><creatorcontrib>Dai, Jing-Cao</creatorcontrib><title>Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework</title><title>Journal of molecular structure</title><description>► One Ag(I) complex built from azelaic acid and 1,3-bis(4-pyridyl)propane was ultrasonically synthesized and characterized. ► Discrete (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters were accommodated in the channels. ► The complex exhibits strong photoluminescence maximized at 500nm upon 350nm excitation. ► CIE chromaticity ordinate of the emission is close to that of edge of green component.
Flexible azelaic acid (H2aze) and 1,3-bis(4-pyridyl)propane) (bpp) react ultrasonically with silver(I) oxide, generating a new metal–organic framework [Ag2(bpp)2(aze)·7H2O·CH3OH]n (1) that forms a 3D supramolecular structure through H-bonding interactions between solvent molecules and carboxylate O atoms with void spaces. Two kinds of solvent clusters, discrete cyclic (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters occupy the channels in the structure. Furthermore, 1 exhibits strong photoluminescence maximized at 500nm upon 350nm excitation at room temperature, of which CIE chromaticity ordinate (x=0.28, y=0.44) is close to that of edge of green component.</description><subject>Atomic structure</subject><subject>Azelate</subject><subject>CIE chromaticity diagram</subject><subject>hydrogen bonding</subject><subject>Methanol–water binary cluster</subject><subject>Photoluminescence</subject><subject>propane</subject><subject>silver</subject><subject>temperature</subject><subject>Water trimer</subject><issn>0022-2860</issn><issn>1872-8014</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PGzEQhi1EpQbav1B8DIddxt6PeG-tokKQkHKgnC3veJY4bNbU3pDCr8er0DOnOczzvqN5GPshIBcg6qttvvN9HMMecwlC5lDmUMEJmwm1kJkCUZ6yGYCUmVQ1fGVnMW4BQKTwjB2Wnv65ONKAxH3H8RV7h3y-XBXr1aWcr-T6UvENjRS8JTQ7CtwMlpsP8GDSho_BTQs38HFDHDdmGKiPU190_QuFzLxRn0jehdRw8OHpG_vSmT7S9495zh6uf_9ZrrK79c3t8tddhlKVY4ZkG1sIU6lCWlUjKZBFiemnVrbQqhJUU2ClbGPKGm3ZYldJsqYwsl5UdVucs_mx9zn4v3uKo965iNT3ZiC_j1pAoeRCNpVIaH1EMfgYA3X6Ob1lwmuC9GRab_V_03oyraHUyXQKXhyDnfHaPAYX9cN9AqpkuW5Us0jEzyORrNCLo6Ajukm5dYFw1Na7z468A306lFI</recordid><startdate>20120815</startdate><enddate>20120815</enddate><creator>Luo, Geng-Geng</creator><creator>Zhu, Rui-Min</creator><creator>He, Wei-Jun</creator><creator>Li, Ming-Zhi</creator><creator>Zhao, Qing-Hua</creator><creator>Li, Dong-Xu</creator><creator>Dai, Jing-Cao</creator><general>Elsevier B.V</general><scope>FBQ</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20120815</creationdate><title>Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework</title><author>Luo, Geng-Geng ; Zhu, Rui-Min ; He, Wei-Jun ; Li, Ming-Zhi ; Zhao, Qing-Hua ; Li, Dong-Xu ; Dai, Jing-Cao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c284t-ced9d31a5832d86ce80234c014b2b0b840893c58d9a46cd4bcf52eda3a26756b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Atomic structure</topic><topic>Azelate</topic><topic>CIE chromaticity diagram</topic><topic>hydrogen bonding</topic><topic>Methanol–water binary cluster</topic><topic>Photoluminescence</topic><topic>propane</topic><topic>silver</topic><topic>temperature</topic><topic>Water trimer</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luo, Geng-Geng</creatorcontrib><creatorcontrib>Zhu, Rui-Min</creatorcontrib><creatorcontrib>He, Wei-Jun</creatorcontrib><creatorcontrib>Li, Ming-Zhi</creatorcontrib><creatorcontrib>Zhao, Qing-Hua</creatorcontrib><creatorcontrib>Li, Dong-Xu</creatorcontrib><creatorcontrib>Dai, Jing-Cao</creatorcontrib><collection>AGRIS</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of molecular structure</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luo, Geng-Geng</au><au>Zhu, Rui-Min</au><au>He, Wei-Jun</au><au>Li, Ming-Zhi</au><au>Zhao, Qing-Hua</au><au>Li, Dong-Xu</au><au>Dai, Jing-Cao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework</atitle><jtitle>Journal of molecular structure</jtitle><date>2012-08-15</date><risdate>2012</risdate><volume>1021</volume><spage>84</spage><epage>88</epage><pages>84-88</pages><issn>0022-2860</issn><eissn>1872-8014</eissn><abstract>► One Ag(I) complex built from azelaic acid and 1,3-bis(4-pyridyl)propane was ultrasonically synthesized and characterized. ► Discrete (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters were accommodated in the channels. ► The complex exhibits strong photoluminescence maximized at 500nm upon 350nm excitation. ► CIE chromaticity ordinate of the emission is close to that of edge of green component.
Flexible azelaic acid (H2aze) and 1,3-bis(4-pyridyl)propane) (bpp) react ultrasonically with silver(I) oxide, generating a new metal–organic framework [Ag2(bpp)2(aze)·7H2O·CH3OH]n (1) that forms a 3D supramolecular structure through H-bonding interactions between solvent molecules and carboxylate O atoms with void spaces. Two kinds of solvent clusters, discrete cyclic (CH3OH)2(H2O)8 heterodecameric and acyclic water trimeric clusters occupy the channels in the structure. Furthermore, 1 exhibits strong photoluminescence maximized at 500nm upon 350nm excitation at room temperature, of which CIE chromaticity ordinate (x=0.28, y=0.44) is close to that of edge of green component.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.molstruc.2012.04.050</doi><tpages>5</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Atomic structure Azelate CIE chromaticity diagram hydrogen bonding Methanol–water binary cluster Photoluminescence propane silver temperature Water trimer |
| title | Coexistence of cyclic (CH3OH)2(H2O)8 heterodecamer and acyclic water trimer in the channels of silver-azelate framework |
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