Synthesis, crystal structure and magnetic properties of new molecular, macrocyclic building blocks of Ni(II) and Cu(II)

► NiII and CuII macrocyclic complexes as new molecular building blocks. ► Weakly interacting paramagnetic centers indicate by magnetic measurements. ► DFT calculation evidence the pathway of the magnetic exchange interactions. ► Good precursors in design and synthesis high spin magnetic materials. N...

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