Three-dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance
A novel nanoarchitectured Sn-Sb-Co alloy electrode is reported, which was prepared by direct electrodeposition on a Cu nanoribbon array in order to target the rapidly fading capacity and the poor rate-capability issues of Sn based materials for Li-ion batteries. The SEM images indicate a three-dimen...
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| Veröffentlicht in: | Journal of materials chemistry 2012-01, Vol.22 (34), p.17511-17517 |
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| container_end_page | 17517 |
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| container_issue | 34 |
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| container_title | Journal of materials chemistry |
| container_volume | 22 |
| creator | Ke, Fu-Sheng Huang, Ling Solomon, Bryan C. Wei, Guo-Zhen Xue, Lian-Jie Zhang, Bo Li, Jun-Tao Zhou, Xiao-Dong Sun, Shi-Gang |
| description | A novel nanoarchitectured Sn-Sb-Co alloy electrode is reported, which was prepared by direct electrodeposition on a Cu nanoribbon array in order to target the rapidly fading capacity and the poor rate-capability issues of Sn based materials for Li-ion batteries. The SEM images indicate a three-dimensional (3D) nanoarchitectured Sn-Sb-Co alloy with an array structure. Electrochemical measurements show that the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) alloy electrode exhibits a reversible capacity as high as 512.8 mA h g super(-1) at 0.2 C (1 C = 650 mA g super(-1)) after 150 cycles. Furthermore, the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) anode can deliver a high reversible capacity (275 mA h g super(-1)) up to the 80 super(th) cycle at a high discharge-charge rate of 23 C ( similar to 15 A g super(-1)). These outstanding electrochemical properties are attributed to the unique nanoarchitectures of the Sn sub(54)Sb sub(41)Co sub( 5) electrodes, making them an excellent anode material. |
| doi_str_mv | 10.1039/c2jm32162a |
| format | Article |
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The SEM images indicate a three-dimensional (3D) nanoarchitectured Sn-Sb-Co alloy with an array structure. Electrochemical measurements show that the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) alloy electrode exhibits a reversible capacity as high as 512.8 mA h g super(-1) at 0.2 C (1 C = 650 mA g super(-1)) after 150 cycles. Furthermore, the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) anode can deliver a high reversible capacity (275 mA h g super(-1)) up to the 80 super(th) cycle at a high discharge-charge rate of 23 C ( similar to 15 A g super(-1)). 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The SEM images indicate a three-dimensional (3D) nanoarchitectured Sn-Sb-Co alloy with an array structure. Electrochemical measurements show that the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) alloy electrode exhibits a reversible capacity as high as 512.8 mA h g super(-1) at 0.2 C (1 C = 650 mA g super(-1)) after 150 cycles. Furthermore, the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) anode can deliver a high reversible capacity (275 mA h g super(-1)) up to the 80 super(th) cycle at a high discharge-charge rate of 23 C ( similar to 15 A g super(-1)). These outstanding electrochemical properties are attributed to the unique nanoarchitectures of the Sn sub(54)Sb sub(41)Co sub( 5) electrodes, making them an excellent anode material.</description><subject>Anodes</subject><subject>Arrays</subject><subject>Electrodes</subject><subject>Lithium-ion batteries</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Three dimensional</subject><subject>Tin base alloys</subject><issn>0959-9428</issn><issn>1364-5501</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNpF0EtLAzEQB_AgCtbqxU-QowireWz2cZTiCwoeWs9Lkp3YlN2kJlnUm0fvfkM_iVurCMMMDD-G4Y_QKSUXlPD6UrN1zxktmNxDE8qLPBOC0H00IbWoszpn1SE6inFNCKVlISboY7kKAFlre3DReic77KTzMuiVTaDTEAB7gxfu6_1zocY281h2nX_DMmLpxvLtj-hsWtmhz8YbWMmUIFiI-GXcYnjV0HXg0h_CMfkgnwBvIBgfeuk0HKMDI7sIJ79zih5vrpezu2z-cHs_u5pnmhV5ykxegTJFCbItREmAlqqqiBEV1dSwUrGcSVMqQQzRnKtcCNCaMlbVeasK3vIpOtvd3QT_PEBMTW_j9j_pwA-xGWOsWEl5Tkd6vqM6-BgDmGYTbC_D24i2rm7-4-bfJEd36g</recordid><startdate>20120101</startdate><enddate>20120101</enddate><creator>Ke, Fu-Sheng</creator><creator>Huang, Ling</creator><creator>Solomon, Bryan C.</creator><creator>Wei, Guo-Zhen</creator><creator>Xue, Lian-Jie</creator><creator>Zhang, Bo</creator><creator>Li, Jun-Tao</creator><creator>Zhou, Xiao-Dong</creator><creator>Sun, Shi-Gang</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20120101</creationdate><title>Three-dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance</title><author>Ke, Fu-Sheng ; Huang, Ling ; Solomon, Bryan C. ; Wei, Guo-Zhen ; Xue, Lian-Jie ; Zhang, Bo ; Li, Jun-Tao ; Zhou, Xiao-Dong ; Sun, Shi-Gang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-f48ebf67ead6570e17b880f581c1f27b242af7b50f0c33b455ecc122894db63d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Anodes</topic><topic>Arrays</topic><topic>Electrodes</topic><topic>Lithium-ion batteries</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Three dimensional</topic><topic>Tin base alloys</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ke, Fu-Sheng</creatorcontrib><creatorcontrib>Huang, Ling</creatorcontrib><creatorcontrib>Solomon, Bryan C.</creatorcontrib><creatorcontrib>Wei, Guo-Zhen</creatorcontrib><creatorcontrib>Xue, Lian-Jie</creatorcontrib><creatorcontrib>Zhang, Bo</creatorcontrib><creatorcontrib>Li, Jun-Tao</creatorcontrib><creatorcontrib>Zhou, Xiao-Dong</creatorcontrib><creatorcontrib>Sun, Shi-Gang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ke, Fu-Sheng</au><au>Huang, Ling</au><au>Solomon, Bryan C.</au><au>Wei, Guo-Zhen</au><au>Xue, Lian-Jie</au><au>Zhang, Bo</au><au>Li, Jun-Tao</au><au>Zhou, Xiao-Dong</au><au>Sun, Shi-Gang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three-dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance</atitle><jtitle>Journal of materials chemistry</jtitle><date>2012-01-01</date><risdate>2012</risdate><volume>22</volume><issue>34</issue><spage>17511</spage><epage>17517</epage><pages>17511-17517</pages><issn>0959-9428</issn><eissn>1364-5501</eissn><abstract>A novel nanoarchitectured Sn-Sb-Co alloy electrode is reported, which was prepared by direct electrodeposition on a Cu nanoribbon array in order to target the rapidly fading capacity and the poor rate-capability issues of Sn based materials for Li-ion batteries. The SEM images indicate a three-dimensional (3D) nanoarchitectured Sn-Sb-Co alloy with an array structure. Electrochemical measurements show that the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) alloy electrode exhibits a reversible capacity as high as 512.8 mA h g super(-1) at 0.2 C (1 C = 650 mA g super(-1)) after 150 cycles. Furthermore, the 3D nanoarchitectured Sn sub(54)Sb sub(41)Co sub( 5) anode can deliver a high reversible capacity (275 mA h g super(-1)) up to the 80 super(th) cycle at a high discharge-charge rate of 23 C ( similar to 15 A g super(-1)). These outstanding electrochemical properties are attributed to the unique nanoarchitectures of the Sn sub(54)Sb sub(41)Co sub( 5) electrodes, making them an excellent anode material.</abstract><doi>10.1039/c2jm32162a</doi><tpages>7</tpages></addata></record> |
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| ispartof | Journal of materials chemistry, 2012-01, Vol.22 (34), p.17511-17517 |
| issn | 0959-9428 1364-5501 |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Anodes Arrays Electrodes Lithium-ion batteries Nanocomposites Nanomaterials Nanostructure Three dimensional Tin base alloys |
| title | Three-dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance |
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