Thermal and Mechanical Analysis of Silver Carbon Nanoparticle-PMMA Nanocomposites Obtained by Miniemulsion Polymerization
Silver/carbon nanoparticle--poly(methyl methacrylate) nanocomposites were obtained by in situ miniemulsion polymerization. It was found by electron microscopy that nanoparticles did not disperse individually but as aggregates; however, notable increments in glass transition temperature in the order...
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Veröffentlicht in: | Polymer journal 2009-01, Vol.41 (10), p.816-821 |
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creator | ZARAGOZA-CONTRERAS, E. Armando HERNANDEZ-ESCOBAR, Claudia A MENDOZA-DUARTE, Mónica E FLORES-GALLARDO, Sergio G IBARRA-GOMEZ, Rigoberto MARQUEZ-LUCERO, Alfredo |
description | Silver/carbon nanoparticle--poly(methyl methacrylate) nanocomposites were obtained by in situ miniemulsion polymerization. It was found by electron microscopy that nanoparticles did not disperse individually but as aggregates; however, notable increments in glass transition temperature in the order of 5 to 15 °C, determined by differential scanning calorimetry, were registered by the addition of small amounts of the nanofiller (0.025, 0.050 or 0.10wt %). Dynamic mechanical analysis indicated gains in mechanical properties, which were related to nanoparticle/polymer interfacial interaction. Results also suggested that dispersion efficiency was a determining aspect in mechanical and thermal performance. |
doi_str_mv | 10.1295/polymj.PJ2009090 |
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Armando ; HERNANDEZ-ESCOBAR, Claudia A ; MENDOZA-DUARTE, Mónica E ; FLORES-GALLARDO, Sergio G ; IBARRA-GOMEZ, Rigoberto ; MARQUEZ-LUCERO, Alfredo</creator><creatorcontrib>ZARAGOZA-CONTRERAS, E. Armando ; HERNANDEZ-ESCOBAR, Claudia A ; MENDOZA-DUARTE, Mónica E ; FLORES-GALLARDO, Sergio G ; IBARRA-GOMEZ, Rigoberto ; MARQUEZ-LUCERO, Alfredo</creatorcontrib><description>Silver/carbon nanoparticle--poly(methyl methacrylate) nanocomposites were obtained by in situ miniemulsion polymerization. It was found by electron microscopy that nanoparticles did not disperse individually but as aggregates; however, notable increments in glass transition temperature in the order of 5 to 15 °C, determined by differential scanning calorimetry, were registered by the addition of small amounts of the nanofiller (0.025, 0.050 or 0.10wt %). Dynamic mechanical analysis indicated gains in mechanical properties, which were related to nanoparticle/polymer interfacial interaction. 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Armando ; HERNANDEZ-ESCOBAR, Claudia A ; MENDOZA-DUARTE, Mónica E ; FLORES-GALLARDO, Sergio G ; IBARRA-GOMEZ, Rigoberto ; MARQUEZ-LUCERO, Alfredo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c463t-c63f9a9aae13f0150120fb66bdbb6273beae21b145c57d91525f916e26e2fc3a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Carbon</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Mechanical analysis</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Silver</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ZARAGOZA-CONTRERAS, E. 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Armando</au><au>HERNANDEZ-ESCOBAR, Claudia A</au><au>MENDOZA-DUARTE, Mónica E</au><au>FLORES-GALLARDO, Sergio G</au><au>IBARRA-GOMEZ, Rigoberto</au><au>MARQUEZ-LUCERO, Alfredo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal and Mechanical Analysis of Silver Carbon Nanoparticle-PMMA Nanocomposites Obtained by Miniemulsion Polymerization</atitle><jtitle>Polymer journal</jtitle><date>2009-01-01</date><risdate>2009</risdate><volume>41</volume><issue>10</issue><spage>816</spage><epage>821</epage><pages>816-821</pages><issn>0032-3896</issn><eissn>1349-0540</eissn><coden>POLJB8</coden><abstract>Silver/carbon nanoparticle--poly(methyl methacrylate) nanocomposites were obtained by in situ miniemulsion polymerization. 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subjects | Applied sciences Carbon Composites Exact sciences and technology Forms of application and semi-finished materials Mechanical analysis Nanocomposites Nanomaterials Nanoparticles Nanostructure Polymer industry, paints, wood Polymerization Silver Technology of polymers |
title | Thermal and Mechanical Analysis of Silver Carbon Nanoparticle-PMMA Nanocomposites Obtained by Miniemulsion Polymerization |
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