Synthesis of a 3D photochromic coordination polymer with an interpenetrating arrangement: crystal engineering for electron transfer between donor and acceptor units

Synthesis of a 3D photochromic coordination polymer with an interpenetrating arrangement: crystal engineering for electron transfer between donor and acceptor units

A new photochromic coordination network is constructed viathe combination of viologen and carboxylate fragments. Close packing of the two-fold diamond-like interwoven mode creates electron transfer bridges for the acceptor and donor components. Radicals are generated upon photoirradiation and are ac...

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Veröffentlicht in:CrystEngComm 2012-01, Vol.14 (16), p.5137-5139
Hauptverfasser: Tan, Yi, Chen, Hengjun, Zhang, Jie, Liao, Shijun, Dai, Jingcao, Fu, Zhiyong
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Sprache:eng
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Color
Coordination polymers
Crystals
Electron transfer
Positioning
Radicals
Synthesis
Three dimensional
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container_end_page 5139
container_issue 16
container_start_page 5137
container_title CrystEngComm
container_volume 14
creator Tan, Yi
Chen, Hengjun
Zhang, Jie
Liao, Shijun
Dai, Jingcao
Fu, Zhiyong
description A new photochromic coordination network is constructed viathe combination of viologen and carboxylate fragments. Close packing of the two-fold diamond-like interwoven mode creates electron transfer bridges for the acceptor and donor components. Radicals are generated upon photoirradiation and are accompanied by a color change from yellow to blue-green.
doi_str_mv 10.1039/c2ce25618e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Color
Coordination polymers
Crystals
Electron transfer
Positioning
Radicals
Synthesis
Three dimensional
title Synthesis of a 3D photochromic coordination polymer with an interpenetrating arrangement: crystal engineering for electron transfer between donor and acceptor units
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