Synchrotron far infrared spectroscopy of the ground, ν5, and ν15 states of thiirane
The high-resolution (0.001 cm(-1)) spectrum of thiirane has been recorded at the far-infrared beamline at the Australian synchrotron between 760-400 cm(-1) and 170-10 cm(-1). Ro-vibrational transitions of the highly Coriolis coupled ν(5) (628.1 cm(-1)) and ν(15) (669.7 cm(-1)) fundamentals, as well...
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| Veröffentlicht in: | The Journal of chemical physics 2012-08, Vol.137 (8), p.084306-084306 |
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| container_end_page | 084306 |
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| container_issue | 8 |
| container_start_page | 084306 |
| container_title | The Journal of chemical physics |
| container_volume | 137 |
| creator | Bane, Michael K Thompson, Christopher D Appadoo, Dominique R T McNaughton, Don |
| description | The high-resolution (0.001 cm(-1)) spectrum of thiirane has been recorded at the far-infrared beamline at the Australian synchrotron between 760-400 cm(-1) and 170-10 cm(-1). Ro-vibrational transitions of the highly Coriolis coupled ν(5) (628.1 cm(-1)) and ν(15) (669.7 cm(-1)) fundamentals, as well as pure rotational far-IR transitions have been assigned, and rotational, centrifugal distortion, and Coriolis interaction parameters determined. ν(15) gains the vast majority of its intensity from an interesting Coriolis intensity stealing mechanism, which is also outlined. |
| doi_str_mv | 10.1063/1.4747191 |
| format | Article |
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Ro-vibrational transitions of the highly Coriolis coupled ν(5) (628.1 cm(-1)) and ν(15) (669.7 cm(-1)) fundamentals, as well as pure rotational far-IR transitions have been assigned, and rotational, centrifugal distortion, and Coriolis interaction parameters determined. ν(15) gains the vast majority of its intensity from an interesting Coriolis intensity stealing mechanism, which is also outlined.</description><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.4747191</identifier><identifier>PMID: 22938232</identifier><language>eng</language><publisher>United States</publisher><subject>Quantum Theory ; Spectroscopy, Fourier Transform Infrared ; Sulfides - chemistry ; Synchrotrons</subject><ispartof>The Journal of chemical physics, 2012-08, Vol.137 (8), p.084306-084306</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22938232$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bane, Michael K</creatorcontrib><creatorcontrib>Thompson, Christopher D</creatorcontrib><creatorcontrib>Appadoo, Dominique R T</creatorcontrib><creatorcontrib>McNaughton, Don</creatorcontrib><title>Synchrotron far infrared spectroscopy of the ground, ν5, and ν15 states of thiirane</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>The high-resolution (0.001 cm(-1)) spectrum of thiirane has been recorded at the far-infrared beamline at the Australian synchrotron between 760-400 cm(-1) and 170-10 cm(-1). 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Ro-vibrational transitions of the highly Coriolis coupled ν(5) (628.1 cm(-1)) and ν(15) (669.7 cm(-1)) fundamentals, as well as pure rotational far-IR transitions have been assigned, and rotational, centrifugal distortion, and Coriolis interaction parameters determined. ν(15) gains the vast majority of its intensity from an interesting Coriolis intensity stealing mechanism, which is also outlined.</abstract><cop>United States</cop><pmid>22938232</pmid><doi>10.1063/1.4747191</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | The Journal of chemical physics, 2012-08, Vol.137 (8), p.084306-084306 |
| issn | 1089-7690 |
| language | eng |
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| source | MEDLINE; AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection |
| subjects | Quantum Theory Spectroscopy, Fourier Transform Infrared Sulfides - chemistry Synchrotrons |
| title | Synchrotron far infrared spectroscopy of the ground, ν5, and ν15 states of thiirane |
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