Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals

The synthesis of rigid-rod, helical isocyanate-based macromonomers was achieved through the polymerization of hexyl isocyanate and 4-phenylbutyl isocyanate, initiated by an exo-norbornene functionalized half-titanocene complex. Sequential ruthenium-mediated ring-opening metathesis polymerization of...

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Veröffentlicht in:	Journal of the American Chemical Society 2012-08, Vol.134 (34), p.14249-14254
Hauptverfasser:	Miyake, Garret M, Weitekamp, Raymond A, Piunova, Victoria A, Grubbs, Robert H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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