Removal and Preconcentration of Cobalt Ions from Aqueous Media Using ImHA Packed Column by On-Line SPE System
This work assesses the use of immobilized humic acid (ImHA) onto aminopropyl silica (APS) as a sorbent for the removal and preconcentration of trace amounts of cobalt ions by on-line solid phase extraction (SPE) technique in the column system prepared in our laboratory. Different parameters, such as...
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| Veröffentlicht in: | Water, air, and soil pollution air, and soil pollution, 2012-09, Vol.223 (7), p.3817-3830 |
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| creator | Ayyildiz, H. Filiz Topkafa, Mustafa Arslan, FatmaNur Durmaz, Fatih Kucukkolbasi, Semahat Tarhan, Ismail Kara, Huseyin |
| description | This work assesses the use of immobilized humic acid (ImHA) onto aminopropyl silica (APS) as a sorbent for the removal and preconcentration of trace amounts of cobalt ions by on-line solid phase extraction (SPE) technique in the column system prepared in our laboratory. Different parameters, such as the effect of the pH, concentration, and flow rate, were studied and throughput was observed by a UV detector. All SPE steps were monitored by breakthrough curves used to visualize distribution of cobalt concentration between mobile and solid phase. The solutions collected from stripping steps were analyzed in atomic absorption spectrometer (AAS) and the amount of sorbed ions was calculated. Sorption characteristics were evaluated by using common adsorption isotherms and Scatchard plot analysis. From the obtained results, it was seen that sorption mechanism of cobalt ions were fitted to Langmuir model on a large scale and thought to be localized. Mean free energy (
E
= 40.82 kJ mol
−1
) calculated from D-R isotherm showed that chemical interactions are more effective than physical interactions. This investigation reveals a new, simple, environmentally friendly, and cost-effective method for removal and preconcentration of cobalt ions from aqueous solutions by a new aminopropyl silica-immobilized humic acid material. |
| doi_str_mv | 10.1007/s11270-012-1150-4 |
| format | Article |
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E
= 40.82 kJ mol
−1
) calculated from D-R isotherm showed that chemical interactions are more effective than physical interactions. This investigation reveals a new, simple, environmentally friendly, and cost-effective method for removal and preconcentration of cobalt ions from aqueous solutions by a new aminopropyl silica-immobilized humic acid material.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-012-1150-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Acids ; Adsorption ; Anabolic steroids ; Analysis ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biomass ; Biomedical materials ; Chemical interactions ; Climate Change/Climate Change Impacts ; Cobalt ; Earth and Environmental Science ; Environment ; Environmental monitoring ; Flow rates ; Free energy ; Heavy metals ; Humic acid ; Humic acids ; Hydrogeology ; Ions ; Isotherms ; Metals ; Pollution ; Silica ; Soil Science & Conservation ; Sorbents ; Sorption ; Spectral analysis ; Studies ; Water Quality/Water Pollution</subject><ispartof>Water, air, and soil pollution, 2012-09, Vol.223 (7), p.3817-3830</ispartof><rights>Springer Science+Business Media B.V. 2012</rights><rights>COPYRIGHT 2012 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c416t-673d43a7cba1f2fb144d0cf1351b1710fc5300c1fbd34b7832fb0f13e405afe43</citedby><cites>FETCH-LOGICAL-c416t-673d43a7cba1f2fb144d0cf1351b1710fc5300c1fbd34b7832fb0f13e405afe43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-012-1150-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-012-1150-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27926,27927,41490,42559,51321</link.rule.ids></links><search><creatorcontrib>Ayyildiz, H. Filiz</creatorcontrib><creatorcontrib>Topkafa, Mustafa</creatorcontrib><creatorcontrib>Arslan, FatmaNur</creatorcontrib><creatorcontrib>Durmaz, Fatih</creatorcontrib><creatorcontrib>Kucukkolbasi, Semahat</creatorcontrib><creatorcontrib>Tarhan, Ismail</creatorcontrib><creatorcontrib>Kara, Huseyin</creatorcontrib><title>Removal and Preconcentration of Cobalt Ions from Aqueous Media Using ImHA Packed Column by On-Line SPE System</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>This work assesses the use of immobilized humic acid (ImHA) onto aminopropyl silica (APS) as a sorbent for the removal and preconcentration of trace amounts of cobalt ions by on-line solid phase extraction (SPE) technique in the column system prepared in our laboratory. Different parameters, such as the effect of the pH, concentration, and flow rate, were studied and throughput was observed by a UV detector. All SPE steps were monitored by breakthrough curves used to visualize distribution of cobalt concentration between mobile and solid phase. The solutions collected from stripping steps were analyzed in atomic absorption spectrometer (AAS) and the amount of sorbed ions was calculated. Sorption characteristics were evaluated by using common adsorption isotherms and Scatchard plot analysis. From the obtained results, it was seen that sorption mechanism of cobalt ions were fitted to Langmuir model on a large scale and thought to be localized. Mean free energy (
E
= 40.82 kJ mol
−1
) calculated from D-R isotherm showed that chemical interactions are more effective than physical interactions. This investigation reveals a new, simple, environmentally friendly, and cost-effective method for removal and preconcentration of cobalt ions from aqueous solutions by a new aminopropyl silica-immobilized humic acid material.</description><subject>Acids</subject><subject>Adsorption</subject><subject>Anabolic steroids</subject><subject>Analysis</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biomass</subject><subject>Biomedical materials</subject><subject>Chemical interactions</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Cobalt</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Flow rates</subject><subject>Free energy</subject><subject>Heavy metals</subject><subject>Humic acid</subject><subject>Humic acids</subject><subject>Hydrogeology</subject><subject>Ions</subject><subject>Isotherms</subject><subject>Metals</subject><subject>Pollution</subject><subject>Silica</subject><subject>Soil Science & Conservation</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Spectral analysis</subject><subject>Studies</subject><subject>Water Quality/Water Pollution</subject><issn>0049-6979</issn><issn>1573-2932</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kV9rHCEUxaW00G2aD9A3oS99MfWqs848LkvaLGzJkj_P4ji6mI6a6mxgv30dNpC2NN4Hwfs718M9CH0CegGUyq8FgElKKDAC0FAi3qAFNJIT1nH2Fi0oFR1ZdrJ7jz6U8kDr6Vq5QOHGhvSkR6zjgHfZmhSNjVPWk08RJ4fXqdfjhDcpFuxyCnj162DToeAfdvAa3xcf93gTrlZ4p81PO1TBeAgR90d8HcnWR4tvd5f49lgmGz6id06PxZ4_32fo_tvl3fqKbK-_b9arLTEClhNZSj4IrqXpNTjmehBioMYBb6AHCdSZhlNqwPUDF71seWVobVtBG-2s4Gfoy2nuY07VbplU8MXYcdRx9q6ActEy2bIZ_fwP-pAOOVZ3M1U5Bnz5Qu31aJWPLtUVmXmoWnHZQCs4ayt18R-q1mCDr5u1ztf3vwRwEpicSsnWqcfsg87H-reac1WnXFXNVc25qtkwO2lKZePe5j8Nvyb6Da7-ofU</recordid><startdate>20120901</startdate><enddate>20120901</enddate><creator>Ayyildiz, H. 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Filiz</au><au>Topkafa, Mustafa</au><au>Arslan, FatmaNur</au><au>Durmaz, Fatih</au><au>Kucukkolbasi, Semahat</au><au>Tarhan, Ismail</au><au>Kara, Huseyin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal and Preconcentration of Cobalt Ions from Aqueous Media Using ImHA Packed Column by On-Line SPE System</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2012-09-01</date><risdate>2012</risdate><volume>223</volume><issue>7</issue><spage>3817</spage><epage>3830</epage><pages>3817-3830</pages><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>This work assesses the use of immobilized humic acid (ImHA) onto aminopropyl silica (APS) as a sorbent for the removal and preconcentration of trace amounts of cobalt ions by on-line solid phase extraction (SPE) technique in the column system prepared in our laboratory. Different parameters, such as the effect of the pH, concentration, and flow rate, were studied and throughput was observed by a UV detector. All SPE steps were monitored by breakthrough curves used to visualize distribution of cobalt concentration between mobile and solid phase. The solutions collected from stripping steps were analyzed in atomic absorption spectrometer (AAS) and the amount of sorbed ions was calculated. Sorption characteristics were evaluated by using common adsorption isotherms and Scatchard plot analysis. From the obtained results, it was seen that sorption mechanism of cobalt ions were fitted to Langmuir model on a large scale and thought to be localized. Mean free energy (
E
= 40.82 kJ mol
−1
) calculated from D-R isotherm showed that chemical interactions are more effective than physical interactions. This investigation reveals a new, simple, environmentally friendly, and cost-effective method for removal and preconcentration of cobalt ions from aqueous solutions by a new aminopropyl silica-immobilized humic acid material.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11270-012-1150-4</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0049-6979 |
| ispartof | Water, air, and soil pollution, 2012-09, Vol.223 (7), p.3817-3830 |
| issn | 0049-6979 1573-2932 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1034827824 |
| source | SpringerNature Journals |
| subjects | Acids Adsorption Anabolic steroids Analysis Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Biomass Biomedical materials Chemical interactions Climate Change/Climate Change Impacts Cobalt Earth and Environmental Science Environment Environmental monitoring Flow rates Free energy Heavy metals Humic acid Humic acids Hydrogeology Ions Isotherms Metals Pollution Silica Soil Science & Conservation Sorbents Sorption Spectral analysis Studies Water Quality/Water Pollution |
| title | Removal and Preconcentration of Cobalt Ions from Aqueous Media Using ImHA Packed Column by On-Line SPE System |
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