Electrochemical and theoretical investigations of the role of the appended base on the reduction of protons by [Fe2(CO)4(κ2-PNP(R)(μ-S(CH2)3S] (PNP(R) ={Ph2PCH2}2NR, R=Me, Ph)

The behavior of [Fe(2)(CO)(4)(κ(2)-PNP(R))(μ-pdt)] (PNP(R) =(Ph(2)PCH(2))(2)NR, R=Me (1), Ph (2); pdt=S(CH(2))(3)S) in the presence of acids is investigated experimentally and theoretically (using density functional theory) in order to determine the mechanisms of the proton reduction steps supported...

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